An estimate, based on Bunsen's analysis of rocks, of the chief elements in the earth's crust, is as follows:—
O, 46 per cent Ca, 3 per cent
Si, 30 per cent Na, 2 per cent
Al, 8 per cent K, 2 per cent
Fe, 6 per cent Mg, 1 per cent
More than half the elements are known to exist in sea-water, and the rest are thought to be there, though dissolved in such small quantity as to elude detection. What four are found in the atmosphere?CHAPTER LIV.
ORGANIC CHEMISTRY.
295. General Considerations.—Inorganic chemistry is the chemistry of minerals, or unorganized bodies. Organic chemistry was formerly defined as the chemistry of the compounds found in plants and animals; but of late it has taken a much wider range, and is now defined as the chemistry of the C compounds, since C is the nucleus around which other elements centre, and with which they combine to form the organic substances. New organic compounds are constantly being discovered and synthesized, so that nearly 100,000 are now known. The molecule of organic matter is often very complex, sometimes containing hundreds of atoms.
In organic as in inorganic chemistry, atoms are bound together by chemical affinity, though it was formerly supposed that an additional or vital force was instrumental in forming organic compounds. For this reason none of these substances, it was thought, could be built up in the laboratory, although many had been analyzed. In 1828 the first organic compound, urea, was artificially prepared, and since then thousands have been synthesized. They are not necessarily manufactured from organic products, but can be made from mineral matter.
296. Molecular Differences.—Molecules may differ in three ways: (1) In the kind of atoms they contain. Compare CO2 and CS2. (2) In the number of atoms. Compare CO and CO2. (3) In the arrangement of atoms, i.e. the molecular structure. Ethyl alcohol and methyl ether have the same number of the same elements, C2H6O, but their molecular structure is not the same, and hence their properties differ.
Qualitative analysis shows what elements enter into a compound; quantitative analysis shows the proportion of these elements; structural analysis exhibits molecular structure, and is the branch to which organic chemists are now giving particular attention. `
A specialist often works for years to synthesize a series of compounds in the laboratory.
297. Sources.—Some organic products are now made in a purer and cheaper form than Nature herself prepares them. Alizarine, the coloring principle of madder, was until lately obtained only from the root of the madder plant; now it is almost wholly manufactured from coal-tar, and the manufactured article serves its purpose much better than the native product. Ten million dollars' worth is annually made, and Holland, the home of the plant, is giving up madder culture. Artificial naphthol-scarlet is abolishing the culture of the cochineal insect. Indigo has also been synthesized. Certain compounds have been predicted from a theoretical molecular structure, then made, and afterwards found to exist in plants. Others are made that have no known natural existence. The source of a large number of artificial organic products is coal-tar, from bituminous coal. Saccharine, a compound with two hundred and eighty times the sweetening power of sugar, is one of its latest products. Wood, bones, and various fermentable liquids are other sources of organic compounds.