An Introduction to Chemical Science

by Rufus P. Williams

(5) How many of HCl? H2O (steam)? CO2? Explain fully every case.

Vapor density is very easily determined from the formula by the method given above. But in practice the formula is obtained from the vapor density, and hence the method there given has to be reversed.

173. Vapor Density of Oxygen.—Suppose we were to obtain the vapor density of O. We should carefully seal and weigh a given volume, say a liter, at a noted temperature and barometric pressure, which are reducedto 0 degrees and 760 mm, and compare it with the weight of the same volume of H. This has been done repeatedly, and O has been found to weigh 16 times as much as H, volume for volume, or, more exactly, 15.96+. Now a liter of each gas has the same number of molecules, therefore the O molecule weighs 16 times the H molecule. The half-molecule of each has the same proportion, and the vapor density of O is 16. Atomic weight is obtained in a very different way.

PROBLEMS.

(1) A liter of Cl is found to weigh 3.195 g. Compute its vapor density, and explain fully.

(2) A liter of Hg vapor, under standard conditions, weighs 9 g. Find its vapor density, and explain.

The vapor density of only a few elements has been satisfactorily determined. See page 12. Some cannot be vaporized; others can be, but only under conditions which prevent weighing them. The vapor density of very many compounds also is unknown.

(3) A liter of CO2 weighs 1.98 g. Find the vapor density, and from that the molecular weight, remembering that the latter is twice the former. See whether it corresponds to that obtained from the formula, CO2. This is,in fact, the way a formula is ascertained, if the atomic weights of its elements are known.

(4) A liter of a compound gas weighs 2.88 g. Analysis shows that its weight is half S and half O. As the atomic weight of S is 32, and that of O is 16, what is the symbol for the gas?

Solution. Its molecular weight is 64, i.e. (2.88=0.09) X 2, of which 32 is S and 32 O. The atomic weight of S is 32, hence there is one atom of S, while of O there are two atoms. The formula is SO2.