G. B. C.
Recovery of Silver from waste Solutions,—from the black Deposit of Hypo Baths, etc.
RECOVERY OF WASTE SILVER, ETC.
The manner for separating metallic silver from waste solutions varies according to the presence or absence of alkaline hyposulphite and cyanides.
a. Separation of metallic Silver from old Nitrate Baths.—The silver contained in solutions of the nitrate, acetate, etc.; may easily be precipitated by suspending a strip of sheet copper in the liquid; the action is completed in two or three days, the whole of the nitric acid and oxygen passing to the copper, and forming a blue solution of the nitrate of copper. The metallic silver however separated in this manner, always contains a portion of copper, and gives a blue solution when dissolved in nitric acid.
A better process is to commence by precipitating the silver entirely in the form of chloride of silver, by adding common salt until no further milkiness can be produced. If the liquid is well stirred, the chloride of silver sinks to the bottom, and may be washed by repeatedly filling the vessel with common water, and pouring off the upper clear portion when the clots have again settled down. The chloride of silver thus formed may afterwards be reduced to metallic silver by a process which will presently be described.
b. Separation of Silver from solutions containing alkaline Hyposulphites, Cyanides or Iodides.—In this case the silver cannot be precipitated by adding chloride of sodium, since the chloride of silver is soluble in such liquids. Therefore it is necessary to use the sulphuretted hydrogen, or the hydrosulphate of ammonia, and to separate the silver in the form of sulphuret.
Sulphuretted hydrogen gas is readily prepared, by fitting a cork and flexible tubing to the neck of a pint bottle, and having introduced sulphuret of iron (sold by operative chemists for the purpose), about as much as will stand in the palm of the hand, pouring upon it 1½ fluid ounces of oil of vitriol diluted with 10 ounces of water. The gas is generated gradually without the application of heat; and must be allowed to bubble up through the liquid from which the silver is to be separated. The smell of sulphuretted hydrogen being offensive, and highly poisonous if inhaled in a concentrated form, the operation must be carried on in the open air, or in a place where the fumes may escape without doing injury.