Ammonia.
Symbol, NH{3} or NH{4}O. Atomic weight, 17.
The liquid known by this name is an aqueous solution of the volatile gas ammonia. Ammoniacal gas contains 1 atom of nitrogen combined with three of hydrogen: these two elementary bodies exhibit no affinity for each other, but they can be made to unite under certain circumstances, and the result is ammonia.
Properties of Ammonia.—Ammoniacal gas is soluble in water to a large extent; the solution possessing those properties which are termed alkaline. Ammonia, however, differs from the other alkalies in one important particular—it is volatile: hence the original color of turmeric paper affected by ammonia is restored on the application of heat. Solution of ammonia absorbs carbonic acid rapidly from the air, and is converted into carbonate of ammonia; it should therefore be preserved in stoppered bottles. Besides carbonate, commercial ammonia often contains chloride of ammonium, recognized by the white precipitate given by nitrate of silver after acidifying with pure nitric acid.
The strength of commercial ammonia varies greatly; that sold for pharmaceutica purposes, under the name of liquor ammoniæ, contains about 10 per cent, of real ammonia. The sp. gr. of aqueous ammonia diminishes with the proportion of ammonia present, the liquor ammoniæ being usually about ·936.
Chemical Properties.—Ammonia, although forming a large class of salts, appears at first sight to contrast strongly by composition with the alkalies proper, such as potash and soda. Mineral bases generally are protoxides of metals, but ammonia consists simply of nitrogen and hydrogen united with oxygen. The following remarks may perhaps tend somewhat to elucidate the difficulty:—
Theory of Ammonium.—This theory supposes that a substance exists possessing the properties of a metal, but different from metallic bodies generally in being compound in structure: the formula assigned to it is NH{4}, 1 atom of nitrogen united with 4 of hydrogen. The hypothetical metal is termed "ammonium," and ammonia, associated with an atom of water, may be viewed as its oxide; for NH{3} + HO plainly equals NH{4}O. Thus, as potash is the oxide of potassium, so ammonia is the oxide of ammonium.
The composition of the salts of ammonia is on this view assimilated to those of the alkalies proper. Thus, sulphate of ammonia is a sulphate of the oxide of ammonium; muriate or hydrochlorate of ammonia is a chloride of ammonium, etc.
Ammonio-Nitrate of Silver.
(See [Silver, Ammonio-Nitrate of.])