If L L be a double convex-lens, and R R R parallel rays of white light, composed of the seven colored rays, each having a different index of refraction, they cannot be refracted to one and the same point; the red rays, being the least refrangible, will be bent to r, and the violet rays, being the most refrangible, to v: the distance v r constitutes the chromatic aberration, and the circle, of which the diameter is a l, the place or point of mean refraction, and is called the circle of least aberration. If the rays of the sun are refracted by means of a lens, and the image received on a screen placed between C and o, so as to cut the cone L a l L, a luminous circle will be formed on the paper, only surrounded by a red border, because it is produced by a section of the cone L a l L, of which the external rays L a L l, are red; if the screen be moved to the other side of o, the luminous circle will be bordered with violet, because it will be a section of the cone M a M l, of which the exterior rays are violet. To avoid the influence of spherical aberration, and to render the phenomena of coloration more evident, let an opaque disc be placed over the central portion of the lens, so as to allow the rays only to pass which are at the edge of the glass; a violet image of the sun will then be seen at v, red at r, and, finally, images of all the colors of the spectrum in the intermediate space; consequently, the general image will not only be confused, but clothed with prismatic colors.”
To overcome the difficulty arising from the chromatic aberration, the optician has only to employ a combination of lenses of opposite focal length, and cut from glass possessing different refrangible powers, so that the rays of light passing through the one are strongly refracted, and in the other are bent asunder again, reproducing white light.
To the photographer one of the most important features, requiring his particular attention, is, that he be provided with a good lens. By the remarks given in the preceding pages, he will be enabled, in a measure, to judge of some of the difficulties to which he is occasionally subjected. We have in this country but two or three individuals who are giving their attention to the manufacture of lenses, and their construction is such, that they are quite free from the spherical or chromatic aberration.
CHAPTER V.
To make Plates for the Daguerreotype—Determining the Time of Exposure in the Camera—Instantaneous Process for Producing Daguerreotype—Galvanizing the Daguerreotype Plate—Silvering Solution—Daguerreotype without Mercury—Management of Chemicals—Hints and Cautions—Electrotyping—Crayon Daguerreotypes—Illuminated Daguerreotypes—Natural Colors in Heliography—Multiplying Daguerreotypes on one Plate—Deposit in Gilding—Practical Hints on the Daguerreotype.
TO MAKE PLATES FOR THE DAGUERREOTYPE.
I do not give the method employed by our regular plate manufacturers; this is not important, as the operator could not possibly profit by it from the fact of the great expense of manufacturing. The following will be found practical:
Procure a well planished copper plate of the required size, and well polish it, first with pumice stone and water, then with snake stone, jewelers’ rouge. Plates can be purchased in a high state of preparation from the engravers. Having prepared the copper-plate, well rub it with salt and water, and then with the silvering powder. No kind answers better than that used by clock-makers to silver their dial-plates. It is composed of one part of well washed chloride of silver, five parts of cream of tartar, and four parts of table salt. This powder must be kept in a dark vessel, and in a dry place. For a plate six inches by five, as much of this composition as can be taken up on a shilling is sufficient. It is to be laid in the centre of the copper, and the figures being wetted, to be quickly rubbed over every part of the plate, adding occasionally a little damp salt. The copper being covered with the silvering is to be speedily well washed in water, in which a little soda is dissolved, and as soon as the surface is of a fine silvery whiteness, it is to be dried with a very clean warm cloth. In this state the plates may be kept for use. The first process is to expose the plate to the heat of a spirit flame, until the silvered surface becomes of a well-defined golden-yellow color; then, when the plate is cold, take a piece of cotton, dipped in very dilute nitric acid, and rub lightly over it until the white hue is restored, and dry it with very soft clean cloths. A weak solution of the hydriodate of potash, in which a small portion of iodine is dissolved, is now passed over the plate with a wide camel’s hair brush. The silver is thus converted, over its surface, into an ioduret of silver; and in this state it is exposed to light, which blackens it. When dry, it is to be again polished, either with dilute acid or a solution of carbonate of soda, and afterwards with dry cotton, and the smallest possible portion of prepared chalk: by this means a surface of the highest polish is produced. The rationale of this process is, in the first place, the heat applied dries off any adhering acid, and effects more perfect union between the copper and silver, so as to enable it to bear the subsequent processes. The first yellow surface appears to be an oxide of silver with, possibly, a minute quantity of copper in combination, which being removed leaves a surface chemically pure.
Another Method.—The best and simplest mode with which we are acquainted is to divide an earthenware vessel with a diaphragm: one side should be filled with a very dilute solution of sulphuric acid, and the other with either a solution of ferroprussiate of potash, or muriate of soda, saturated with chloride of silver. The copper plate, varnished on one side, is united, by means of a copper wire, with a plate of zinc. The zinc plate being immersed in the acid, and the copper in the salt, a weak electric current is generated, which precipitates the silver in a very uniform manner over the entire surface.