Some experiments that have a bearing on the efficacy of this compost will be detailed presently.
There is no doubt that the soluble and more active (caustic) forms of alkaline bodies exert a powerful decomposing and solvent action on peat. It is asserted too that the nearly insoluble and less active matters of this kind, also have an effect, though a less complete and rapid one. Thus, carbonate of lime in the various forms of chalk, shell marl,[6] old mortar, leached ashes and peat ashes, (for in all these it is the chief and most "alkaline" ingredient,) is recommended to compost with peat. Let us inquire whether carbonate of lime can really exert any noticeable influence in improving the fertilizing quality of peat.
In the case of vitriol peats, carbonate of lime is the cheapest and most appropriate means of destroying the noxious sulphate of protoxide of iron, and correcting their deleterious quality. When carbonate of lime is brought in contact with sulphate of protoxide of iron, the two bodies mutually decompose, with formation of sulphate of lime (gypsum) and carbonate of protoxide of iron. The latter substance absorbs oxygen from the air with the utmost avidity, and passes into the peroxide of iron, which is entirely inert.
The admixture of any earthy matter with peat, will facilitate its decomposition, and make it more active chemically, in so far as it promotes the separation of the particles of the peat from each other, and the consequent access of air. This benefit may well amount to something when we add to peat one-fifth of its bulk of marl or leached ashes, but the question comes up: Do these insoluble mild alkalies exert any direct action? Would not as much soil of any kind be equally efficacious, by promoting to an equal degree the contact of oxygen from the atmosphere?
There are two ways in which carbonate of lime may exert a chemical action on the organic matters of peat. Carbonate of lime, itself, in the forms we have mentioned, is commonly called insoluble in water. It is, however, soluble to a very slight extent; it dissolves, namely, in about 30,000 times its weight of pure water. It is nearly thirty times more soluble in water saturated with carbonic acid; and this solution has distinct alkaline characters. Since the water contained in a heap of peat must be considerably impregnated with carbonic acid, it follows that when carbonate of lime is present, the latter must form a solution, very dilute indeed, but still capable of some direct effect on the organic matters of the peat, when it acts through a long space of time. Again, it is possible that the solution of carbonate of lime in carbonic acid, may act to liberate some ammonia from the soluble portions of the peat, and this ammonia may react on the remainder of the peat to produce the same effects as it does in the case of a compost made with animal matters.
Whether the effects thus theoretically possible, amount to anything practically important, is a question of great interest. It often happens that opinions entertained by practical men, not only by farmers, but by mechanics and artisans as well, are founded on so untrustworthy a basis, are supported by trials so destitute of precision, that their accuracy may well be doubted, and from all the accounts I have met with, it does not seem to have been well established, practically, that composts made with carbonate of lime, are better than the peat and carbonate used separately.
Carbonate of lime (leached ashes, shell marl, etc.), is very well to use in conjunction with peat, to furnish a substance or substances needful to the growth of plants, and supply the deficiencies of peat as regards composition. Although in the agricultural papers, numerous accounts of the efficacy of such mixtures are given, we do not learn from them whether these bodies exert any such good effect upon the peat itself, as to warrant the trouble of making a compost.
4.—Experiments by the author on the effect of alkaline bodies in developing the fertilizing power of Peat.
During the summer of 1862, the author undertook a series of experiments with a view of ascertaining the effect of various composting materials upon peat.
Two bushels of peat were obtained from a heap that had been weathering for some time on the "Beaver Meadow," near New Haven. This was thoroughly air-dried, then crushed by the hand, and finally rubbed through a moderately fine sieve. In this way, the peat was brought to a perfectly homogeneous condition.