Salt-mud.—In the marshes, bays, and estuaries along the sea-shore, accumulate large quantities of fine silt, brought down by rivers or deposited from the sea-water, which are more or less mixed with finely divided peat or partly decomposed vegetable matters, derived largely from Sea-weed, and in many cases also with animal remains (mussels and other shell-fish, crabs, and myriads of minute organisms.) This black mud has great value as a fertilizer.
4. The Chemical Characters and Composition of Peat.
The process of burning, demonstrates that peat consists of two kinds of substance; one of which, the larger portion, is combustible, and is organic or vegetable matter; the other, smaller portion, remaining indestructible by fire is inorganic matter or ash. We shall consider these separately.
a. The organic or combustible part of peat varies considerably in its proximate composition. It is in fact an indefinite mixture of several or perhaps of many compound bodies, whose precise nature is little known. These bodies have received the collective names Humus and Geine. We shall employ the term humus to designate this mixture, whether occurring in peat, swamp-muck, salt-mud, in composts, or in the arable soil. Its chemical characters are much the same, whatever its appearance or mode of occurrence; and this is to be expected since it is always formed from the same materials and under essentially similar conditions.
Resinous and Bituminous matters.—If dry pulverized peat be agitated and warmed for a short time with alcohol, there is usually extracted a small amount of resinous and sometimes of bituminous matters, which are of no account in the agricultural applications of peat, but have a bearing on its value as fuel.
Ulmic and Humic acids.—On boiling what remains from the treatment with alcohol, with a weak solution of carbonate of soda (sal-soda), we obtain a yellowish-brown or black liquid. This liquid contains certain acid ingredients of the peat which become soluble by entering into chemical combination with soda.
On adding to the solution strong vinegar, or any other strong acid, there separates a bulky brown or black substance, which, after a time, subsides to the bottom of the vessel as a precipitate, to use a chemical term, leaving the liquid of a more or less yellow tinge. This deposit, if obtained from light brown peat, is ulmic acid; if from black peat, it is humic acid. These acids, when in the precipitated state, are insoluble in vinegar; but when this is washed away, they are considerably soluble in water. They are, in fact, modified by the action of the soda, so as to acquire much greater solubility in water than they otherwise possess. On drying the bulky bodies thus obtained, brown or black lustrous masses result, which have much the appearance of coal.
Ulmin and Humin.—After extracting the peat with solution of carbonate of soda, it still contains ulmin or humin. These bodies cannot be obtained in the pure state from peat, since they are mixed with more or less partially decomposed vegetable matters from which they cannot be separated without suffering chemical change. They have been procured, however, by the action of muriatic acid on sugar. They are indifferent in their chemical characters, are insoluble in water and in solution of carbonate of soda; but upon heating with solution of hydrate of soda they give dark-colored liquids, being in fact converted by this treatment into ulmic and humic acids, respectively, with which they are identical in composition.
The terms ulmic and humic acids do not refer each to a single compound, but rather to a group of bodies of closely similar appearance and properties, which, however, do differ slightly in their characteristics, and differ also in composition by containing more or less of oxygen and hydrogen in equal equivalents.
After complete extraction with hydrate of soda, there remains more or less undecomposed vegetable matter, together with sand and soil, were these contained in the peat.