Fig. 6. Daniell Cell.
§ 25. The original form given to this, the Daniell cell, is shown at [Fig. 6], in which Z is the zinc rod standing in the porous pot P, in which is placed the dilute sulphuric acid. A containing vessel, V, of glazed earthenware, provided with a perforated shelf, S, on which are placed the crystals of sulphate of copper, serves
to hold the copper sheet, C, and the solution of sulphate of copper. T and T' are the terminals from which the electricity is led where desired.
In another form, the copper sheet itself takes the form and replaces the containing vessel V; and since the copper is not corroded, but actually increases in thickness during action, this is a decided advantage. A modification, in which the porous cell is replaced by sand or by sawdust, is also constructed, and known as "Minotto's" cell: this, owing to the greater thickness of the porous layer, offers more resistance, and gives, consequently, less current. By taking advantage of the greater specific gravity (weight, bulk for bulk) of the solution of sulphate of copper over that of water or dilute sulphuric acid, it is possible to construct a battery which shall act in a manner precisely similar to a Daniell, without the employment of any porous partition whatsoever. [Fig. 7] illustrates the construction of one of these, known as "Gravity Daniells."
Fig. 7. Gravity Cell.
In this we have a plate, disc, or spiral of copper, C, connected by an insulated copper wire to the terminal T'. Over this is placed a layer of crystals of copper sulphate; the jar is then filled nearly to the top with dilute sulphuric acid, or with a strong solution of sulphate of zinc (which is more lasting in its effects, but not so energetic as the dilute sulphuric acid), and on the surface of this, connected to the other terminal, T, is allowed to rest a thick disc of zinc, Z. Speaking of these cells, Professor Ayrton, in his invaluable "Practical Electricity," says:—"All gravity cells have the disadvantage that
they cannot be moved about; otherwise the liquids mix, and the copper sulphate solution, coming into contact with the zinc plate, deposits copper on it. This impairs the action, by causing the zinc to act electrically, like a copper one. Indeed, without any shaking, the liquids mix by diffusion, even when a porous pot is employed; hence a Daniell's cell is found to keep in better order if it be always allowed to send a weak current when not in use, since the current uses up the copper sulphate solution, instead of allowing it to diffuse." The use of a solution of zinc sulphate to act on the zinc rod, or plate, is always to be preferred in the Daniell cell, when long duration is of more consequence than energetic action.