Michael Faraday, His Life and Work

by Silvanus P. Thompson

The laboratory notebook for March to August, 1838, shows a long research, occupying nearly 100 folio pages, on the relation of specific inductive capacity to crystalline structure. This is followed by some experiments upon an electric eel, at the Royal Adelaide Gallery, with some unpublished sketches of the distribution in the water of the currents it emits. He proved, with great satisfaction, that the currents it gave were capable of producing magnetic effects, sparks, and chemical decomposition. These observations were embodied in the fifteenth series of memoirs.

One entry in the laboratory book, of date April 5th, 1838, is of great interest, as showing how his mind ever recurred to the possibility of finding a connection between optical and electric phenomena: “Must try polarized light across a crystalline dielectric under charge. Good reasons perhaps now evident why a non-crystalline dielectric should have no effect.”

Faraday was now feeling greatly the strain of all these years of work, and in 1839 did little research until the autumn. Then he returned to the question of the origin of the electromotive force of the voltaic cell, and by the end of the year completed two long papers on this vexed question; they formed the sixteenth and seventeenth series, and conclude the memoirs of this second period.

THE CONTACT THEORY OF ELECTRICITY.

In the eighth series, completed in April, 1834, on the “Electricity of the Voltaic Pile,” Faraday had dealt with the question—at that time a topic of excited controversy—of the origin of the electromotive force in a cell, Volta, who knew nothing of the chemical actions, ascribed it to the contact of dissimilar metals, whilst Wollaston, Becquerel, and De la Rive considered it the result of chemical actions. The controversy has long ceased to interest the scientific world; for, with the recognition of the principle of the conservation of energy, it became evident that mere contact cannot provide a continuing supply of energy. It would now be altogether dead but for the survival of a belief in the contact theory on the part of one of the most honoured veterans in science. But in the years 1834 to 1840 it was of absorbing interest. Faraday’s work quietly removed the props which supported the older theory, and it crumbled away. He found that the chemical and electrical effects in the cell were proportional one to the other, and inseparable. He discovered a way of making a cell without any metallic contacts. He showed that without chemical action there was no current produced. But his results were ignored for the time. After six years Faraday reopened the question. Again the admirable summary of Professor Tyndall is drawn upon for the following account:—

The memoir on the “Electricity of the Voltaic Pile,” published in 1834, appears to have produced but little impression upon the supporters of the contact theory. These indeed were men of too great intellectual weight and insight lightly to take up, or lightly to abandon, a theory. Faraday therefore resumed the attack in two papers communicated to the Royal Society on February 6 and March 19, 1840. In these papers he hampered his antagonists by a crowd of adverse experiments. He hung difficulty after difficulty about the neck of the contact theory, until in its efforts to escape from his assaults it so changed its character as to become a thing totally different from the theory proposed by Volta. The more persistently it was defended, however, the more clearly did it show itself to be a congeries of devices, bearing the stamp of dialectic skill rather than that of natural truth.

In conclusion, Faraday brought to bear upon it an argument which, had its full weight and purport been understood at the time, would have instantly decided the controversy. “The contact theory,” he urged, “assumes that a force which is able to overcome powerful resistance, as for instance that of the conductors, good or bad, through which the current passes, and that again of the electrolytic action where bodies are decomposed by it, can arise out of nothing; that without any change in the acting matter, or the consumption of any generating force, a current shall be produced which shall go on for ever against a constant resistance, or only be stopped, as in the voltaic trough, by the ruins which its exertion has heaped up in its own course. This would indeed be a creation of power, and is like no other force in nature. We have many processes by which the form of the power may be so changed, that an apparent conversion of one into the other takes place. So we can change chemical force into the electric current, or the current into chemical force. The beautiful experiments of Seebeck and Peltier show the convertibility of heat and electricity; and others by Oersted and myself show the convertibility of electricity and magnetism. But in no case, not even in those of the gymnotus and torpedo, is there a pure creation or a production of power without a corresponding exhaustion of something to supply it.”

In 1839 Faraday gave five Friday discourses and a course of eight afternoon lectures on the non-metallic elements. In 1840 he gave three Friday discourses and seven lectures on chemical affinity. But in the summer came the serious breakdown alluded to on page 75. He did no experimental work after September 14th, nor indeed for nearly two years. Even then it was only a temporary return to research to investigate the source of the electrification produced by steam in the remarkable experiments of Mr. (afterwards Lord) Armstrong. He proved it to be due to friction. This done, he continued to rest from research until the middle of 1844, though he lectured a little for the Royal Institution. In 1841 he gave the juvenile lectures. In 1842 he gave two Friday discourses, one of them being on the lateral discharge in lightning-rods. He also gave the Christmas lectures on electricity.

END OF SECOND ACTIVE PERIOD.

In 1843 he gave three Friday discourses, one of which was on the electricity generated by a jet of steam; and repeated the eight afternoon lectures he had given in 1838. In 1844 he gave eight lectures on heat and two Friday discourses. He also resumed research on the condensation of gases, and vainly tried to liquefy oxygen and hydrogen, though he succeeded with ammonia and nitrous oxide.