-rule associates the greater energy with the shorter vibration period, bluer light gives the more intense energy. Experiments show that (after deducting a constant “threshold” energy used up in extricating the electron from the film) each electron comes out with a kinetic energy equal to the energy of the quantum of incident light.
The film can be prepared in the dark; but on exposure to feeble light electrons immediately begin to fly out before any of the collection-boxes could have been filled by fair means. Nor can we appeal to any trigger action of the light releasing an electron already loaded up with energy for its journey; it is the nature of the light which settles the amount of the load. The light calls the tune, therefore the light must pay the piper. Only classical theory does not provide light with a pocket to pay from.
It is always difficult to make a fence of objections so thorough as to rule out all progress along a certain line of explanation. But even if it is still possible to wriggle on, there comes a time when one begins to perceive that the evasions are far-fetched. If we have any instinct that can recognise a fundamental law of Nature when it sees one, that instinct tells us that the interaction of radiation and matter in single quanta is something lying at the root of world-structure and not a casual detail in the mechanism of the atom. Accordingly we turn to the “sweepstake” theory, which sees in this phenomenon a starting-point for a radical revision of the classical conceptions.
Suppose that the light-waves are of such intensity that, according to the usual reckoning of their energy, one-millionth of a quantum is brought within range of each atom. The unexpected phenomenon is that instead of each atom absorbing one-millionth of a quantum, one atom out of every million absorbs a whole quantum. That whole quanta are absorbed is shown by the photoelectric experiments already described, since each of the issuing electrons has managed to secure the energy of a whole quantum.
It would seem that what the light-waves were really bearing within reach of each atom was not a millionth of a quantum but a millionth chance of securing a whole quantum. The wave-theory of light pictures and describes something evenly distributed over the whole wave-front which has usually been identified with energy. Owing to well-established phenomena such as interference and diffraction it seems impossible to deny this uniformity, but we must give it another interpretation; it is a uniform chance of energy. Following the rather old-fashioned definition of energy as “capacity for doing work” the waves carry over their whole front a uniform chance of doing work. It is the propagation of a chance which the wave-theory studies.
Different views may be held as to how the prize-drawing is conducted on the sweepstake theory. Some hold that the lucky part of the wave-front is already marked before the atom is reached. In addition to the propagation of uniform waves the propagation of a photon or “ray of luck” is involved. This seems to me out of keeping with the general trend of the modern quantum theory; and although most authorities now take this view, which is said to be indicated definitely by certain experiments, I do not place much reliance on the stability of this opinion.
Theory of the Atom. We return now to further experimental knowledge of quanta. The mysterious quantity
crops up inside the atom as well as outside it. Let us take the simplest of all atoms, namely, the hydrogen atom. This consists of a proton and an electron, that is to say a unit charge of positive electricity and a unit charge of negative electricity. The proton carries nearly all the mass of the atom and remains rock-like at the centre, whilst the nimble electron moves round in a circular or elliptic orbit under the inverse-square law of attraction between them. The system is thus very like a sun and a planet. But whereas in the solar system the planet’s orbit may be of any size and any eccentricity, the electron’s orbit is restricted to a definite series of sizes and shapes. There is nothing in the classical theory of electromagnetism to impose such a restriction; but the restriction exists, and the law imposing it has been discovered. It arises because the atom is arranging to make something in its interior equal to