rule.
“Preposterous! You cannot seriously mean that the electron does different things on different days of the week!”
But did I say that it does different things? I used different words to describe its doings. I run down the stairs on Tuesday and slide down the banisters on Wednesday; but if the staircase consists of innumerable infinitesimal steps, there is no essential difference in my mode of progress on the two days. And so it makes no difference whether the electron steps from one orbit to the next lower or comes down in a spiral when the number of steps is innumerably great. The succession of lumps of energy cast overboard merges into a continuous outflow. If you had the formulae before you, you would find that the period of the light and the strength of radiation are the same whether calculated by the Monday or the Tuesday method—but only when the quantum number is infinitely great. The disagreement is not very serious when the number is moderately large; but for small quantum numbers the atom cannot sit on the fence. It has to decide between Monday (classical) and Tuesday (quantum) rules. It chooses Tuesday rules.
If, as we believe, this example is typical, it indicates one direction which the reconstruction of ideas must take. We must not try to build up from classical conceptions, because the classical laws only become true and the conceptions concerned in them only become defined in the limiting case when the quantum numbers of the system are very large. We must start from new conceptions appropriate to low as well as to high numbered states; out of these the classical conceptions should emerge, first indistinctly, then definitely, as the number of the state increases, and the classical laws become more and more nearly true. I cannot foretell the result of this remodelling, but presumably room must be found for a conception of “states”, the unity of a state replacing the kind of tie expressed by classical forces. For low numbered states the current vocabulary of physics is inappropriate; at the moment we can scarcely avoid using it, but the present contradictoriness of our theories arises from this misuse. For such states space and time do not exist—at least I can see no reason to believe that they do. But it must be supposed that when high numbered states are considered there will be found in the new scheme approximate counterparts of the space and time of current conception—something ready to merge into space and time when the state numbers are infinite. And simultaneously the interactions described by transitions of states will merge into classical forces exerted across space and time. So that in the limit the classical description becomes an available alternative. Now in practical experience we have generally had to deal with systems whose ties are comparatively loose and correspond to very high quantum numbers; consequently our first survey of the world has stumbled across the classical laws and our present conceptions of the world consist of those entities which only take definite shape for high quantum numbers. But in the interior of the atom and molecule, in the phenomena of radiation, and probably also in the constitution of very dense stars such as the Companion of Sirius, the state numbers are not high enough to admit this treatment. These phenomena are now forcing us back to the more fundamental conceptions out of which the classical conceptions (sufficient for the other types of phenomena) ought to emerge as one extreme limit.
For an example I will borrow a quantum conception from the [next chapter]. It may not be destined to survive in the present rapid evolution of ideas, but at any rate it will illustrate my point. In Bohr’s semi-classical model of the hydrogen atom there is an electron describing a circular or elliptic orbit. This is only a model; the real atom contains nothing of the sort. The real atom contains something which it has not entered into the mind of man to conceive, which has, however, been described symbolically by Schrödinger. This “something” is spread about in a manner by no means comparable to an electron describing an orbit. Now excite the atom into successively higher and higher quantum states. In the Bohr model the electron leaps into higher and higher orbits. In the real atom Schrödinger’s “something” begins to draw itself more and more together until it begins sketchily to outline the Bohr orbit and even imitates a condensation running round. Go on to still higher quantum numbers, and Schrödinger’s symbol now represents a compact body moving round in the same orbit and the same period as the electron in Bohr’s model, and moreover radiating according to the classical laws of an electron. And so when the quantum number reaches infinity, and the atom bursts, a genuine classical electron flies out. The electron, as it leaves the atom, crystallises out of Schrödinger’s mist like a genie emerging from his bottle.
[31] Prof. E. T. Whittaker.
[32] Since the
rule is now well established the energies of different states of the atoms are usually calculated by its aid; to use these to test the rule would be a vicious circle.