Cementing of particles.—It is chiefly in the case of calcareous rocks that solidification takes place at the time of deposition. But there are many deposits in which a cementing process comes into operation long afterwards. We may sometimes observe, where the water of ferruginous or calcareous springs has flowed through a bed of sand or gravel, that iron or carbonate of lime has been deposited in the interstices between the grains or pebbles, so that in certain places the whole has been bound together into a stone, the same set of strata remaining in other parts loose and incoherent.

Proofs of a similar cementing action are seen in a rock at Kelloway in Wiltshire. A peculiar band of sandy strata, belonging to the group called Oolite by geologists, may be traced through several counties, the sand being for the most part loose and unconsolidated, but becoming stony near Kelloway. In this district there are numerous fossil shells which have decomposed, having for the most part left only their casts. The calcareous matter hence derived has evidently served, at some former period, as a cement to the siliceous grains of sand, and thus a solid sandstone has been produced. If we take fragments of many other argillaceous grits, retaining the casts of shells, and plunge them into dilute muriatic or other acid, we see them immediately changed into common sand and mud; the cement of lime, derived from the shells, having been dissolved by the acid.

Traces of impressions and casts are often extremely faint. In some loose sands of recent date we meet with shells in so advanced a stage of decomposition as to crumble into powder when touched. It is clear that water percolating such strata may soon remove the calcareous matter of the shell; and, unless circumstances cause the carbonate of lime to be again deposited, the grains of sand will not be cemented together; in which case no memorial of the fossil will remain. The absence of organic remains from many aqueous rocks may be thus explained; but we may presume that in many of them no fossils were ever imbedded, as there are extensive tracts on the bottoms of existing seas even of moderate depth on which no fragment of shell, coral, or other living creature can be detected by dredging. On the other hand, there are depths where the zero of animal life has been approached; as, for example, in the Mediterranean, at the depth of about 230 fathoms, according to the researches of Prof. E. Forbes. In the Ægean Sea a deposit of yellowish mud of a very uniform character, and closely resembling chalk, is going on in regions below 230 fathoms, and this formation must be wholly devoid of organic remains.[35-A]

In what manner silex and carbonate of lime may become widely diffused in small quantities through the waters which permeate the earth's crust will be spoken of presently, when the petrifaction of fossil bodies is considered; but I may remark here that such waters are always passing in the case of thermal springs from hotter to colder parts of the interior of the earth; and as often as the temperature of the solvent is lowered, mineral matter has a tendency to separate from it and solidify. Thus a stony cement is often supplied to any sand, pebbles, or fragmentary mixture. In some conglomerates, like the pudding-stone of Hertfordshire, pebbles of flint and grains of sand are united by a siliceous cement so firmly, that if a block be fractured the rent passes as readily through the pebbles as through the cement.

It is probable that many strata became solid at the time when they emerged from the waters in which they were deposited, and when they first formed a part of the dry land. A well-known fact seems to confirm this idea: by far the greater number of the stones used for building and road-making are much softer when first taken from the quarry than after they have been long exposed to the air; and these, when once dried, may afterwards be immersed for any length of time in water without becoming soft again. Hence it is found desirable to shape the stones which are to be used in architecture while they are yet soft and wet, and while they contain their "quarry-water," as it is called; also to break up stone intended for roads when soft, and then leave it to dry in the air for months that it may harden. Such induration may perhaps be accounted for by supposing the water, which penetrates the minutest pores of rocks, to deposit, on evaporation, carbonate of lime, iron, silex, and other minerals previously held in solution, and thereby to fill up the pores partially. These particles, on crystallizing, would not only be themselves deprived of freedom of motion, but would also bind together other portions of the rock which before were loosely aggregated. On the same principle wet sand and mud become as hard as stone when frozen; because one ingredient of the mass, namely, the water, has crystallized, so as to hold firmly together all the separate particles of which the loose mud and sand were composed.

Dr. MacCulloch mentions a sandstone in Skye, which may be moulded like dough when first found; and some simple minerals, which are rigid and as hard as glass in our cabinets, are often flexible and soft in their native beds; this is the case with asbestos, sahlite, tremolite, and chalcedony, and it is reported also to happen in the case of the beryl.[36-A]

The marl recently deposited at the bottom of Lake Superior, in North America, is soft, and often filled with freshwater shells; but if a piece be taken up and dried, it becomes so hard that it can only be broken by a smart blow of the hammer. If the lake therefore was drained, such a deposit would be found to consist of strata of marlstone, like that observed in many ancient European formations, and like them containing freshwater shells.[36-B]

It is probable that some of the heterogeneous materials which rivers transport to the sea may at once set under water, like the artificial mixture called pozzolana, which consists of fine volcanic sand charged with about 20 per cent. of oxide of iron, and the addition of a small quantity of lime. This substance hardens, and becomes a solid stone in water, and was used by the Romans in constructing the foundations of buildings in the sea.

Consolidation in these cases is brought about by the action of chemical affinity on finely comminuted matter previously suspended in water. After deposition similar particles seem to exert a mutual attraction on each other, and congregate together in particular spots, forming lumps, nodules, and concretions. Thus in many argillaceous deposits there are calcareous balls, or spherical concretions, ranged in layers parallel to the general stratification; an arrangement which took place after the shale or marl had been thrown down in successive laminæ; for these laminæ are often traced in the concretions, remaining parallel to those of the surrounding unconsolidated rock. (See [fig. 55.]) Such nodules of limestone have often a shell or other foreign body in the centre.[37-A]