The student may perhaps ask whether, on chemical principles, we have any ground to expect that mineral matter will be thrown down precisely in those spots where organic decomposition is in progress? The following curious experiments may serve to illustrate this point. Professor Göppert of Breslau attempted recently to imitate the natural process of petrifaction. For this purpose he steeped a variety of animal and vegetable substances in waters, some holding siliceous, others calcareous, others metallic matter in solution. He found that in the period of a few weeks, or even days, the organic bodies thus immersed were mineralized to a certain extent. Thus, for example, thin vertical slices of deal, taken from the Scotch fir (Pinus sylvestris), were immersed in a moderately strong solution of sulphate of iron. When they had been thoroughly soaked in the liquid for several days they were dried and exposed to a red-heat until the vegetable matter was burnt up and nothing remained but an oxide of iron, which was found to have taken the form of the deal so exactly that casts even of the dotted vessels peculiar to this family of plants were distinctly visible under the microscope.
Another accidental experiment has been recorded by Mr. Pepys in the Geological Transactions.[41-A] An earthen pitcher containing several quarts of sulphate of iron had remained undisturbed and unnoticed for about a twelvemonth in the laboratory. At the end of this time when the liquor was examined an oily appearance was observed on the surface, and a yellowish powder, which proved to be sulphur, together with a quantity of small hairs. At the bottom were discovered the bones of several mice in a sediment consisting of small grains of pyrites, others of sulphur, others of crystallized green sulphate of iron, and a black muddy oxide of iron. It was evident that some mice had accidentally been drowned in the fluid, and by the mutual action of the animal matter and the sulphate of iron on each other, the metallic sulphate had been deprived of its oxygen; hence the pyrites and the other compounds were thrown down. Although the mice were not mineralized, or turned into pyrites, the phenomenon shows how mineral waters, charged with sulphate of iron, may be deoxydated on coming in contact with animal matter undergoing putrefaction, so that atom after atom of pyrites may be precipitated, and ready, under favourable circumstances, to replace the oxygen, hydrogen, and carbon into which the original body would be resolved.
The late Dr. Turner observes, that when mineral matter is in a "nascent state," that is to say, just liberated from a previous state of chemical combination, it is most ready to unite with other matter, and form a new chemical compound. Probably the particles or atoms just set free are of extreme minuteness, and therefore move more freely, and are more ready to obey any impulse of chemical affinity. Whatever be the cause, it clearly follows, as before stated, that where organic matter newly imbedded in sediment is decomposing, there will chemical changes take place most actively.
An analysis was lately made of the water which was flowing off from the rich mud deposited by the Hooghly river in the Delta of the Ganges after the annual inundation. This water was found to be highly charged with carbonic acid gas holding lime in solution.[41-B] Now if newly-deposited mud is thus proved to be permeated by mineral matter in a state of solution, it is not difficult to perceive that decomposing organic bodies, naturally imbedded in sediment, may as readily become petrified as the substances artificially immersed by Professor Göppert in various fluid mixtures.
It is well known that the water of springs, or that which is continually percolating the earth's crust, is rarely free from a slight admixture either of iron, carbonate of lime, sulphur, silica, potash, or some other earthy, alkaline, or metallic ingredient. Hot springs in particular are copiously charged with one or more of these elements; and it is only in their waters that silex is found in abundance. In certain cases, therefore, especially in volcanic regions, we may imagine the flint of silicified wood and corals to have been supplied by the waters of thermal springs. In other instances, as in tripoli and chalk-flint, it may have been derived in great part, if not wholly, from the decomposition of infusoria or diatomaceæ, sponges, and other bodies. But even if this be granted, we have still to inquire whence a lake or the ocean can be constantly replenished with the calcareous and siliceous matter so abundantly withdrawn from it by the secretions of these zoophytes.
In regard to carbonate of lime there is no difficulty, because not only are calcareous springs very numerous, but even rain-water has the power of dissolving a minute portion of the calcareous rocks over which it flows. Hence marine corals and mollusca may be provided by rivers with the materials of their shells and solid supports. But pure silex, even when reduced to the finest powder and boiled, is insoluble in water, except at very high temperatures. Nevertheless Dr. Turner has well explained, in an essay on the chemistry of geology[42-A], how the decomposition of felspar may be a source of silex in solution. He has remarked that the siliceous earth, which constitutes more than half the bulk of felspar, is intimately combined with alumine, potash, and some other elements. The alkaline matter of the felspar has a chemical affinity for water, as also for the carbonic acid which is more or less contained in the waters of most springs. The water therefore carries away alkaline matter, and leaves behind a clay consisting of alumine and silica. But this residue of the decomposed mineral, which in its purest state is called porcelain clay, is found to contain a part only of the silica which existed in the original felspar. The other part, therefore, must have been dissolved and removed; and this can be accounted for in two ways; first, because silica when combined with an alkali is soluble in water; secondly, because silica in what is technically called its nascent state is also soluble in water. Hence an endless supply of silica is afforded to rivers and the waters of the sea. For the felspathic rocks are universally distributed, constituting, as they do, so large a proportion of the volcanic, plutonic, and metamorphic formations. Even where they chance to be absent in mass, they rarely fail to occur in the superficial gravel or alluvial deposits of the basin of every large river.
The disintegration of mica also, another mineral which enters largely into the composition of granite and various sandstones, may yield silica which may be dissolved in water, for nearly half of this mineral consists of silica, combined with alumine, potash, and about a tenth part of iron. The oxidation of this iron in the air is the principal cause of the waste of mica.
We have still, however, much to learn before the conversion of fossil bodies into stone is fully understood. Some phenomena seem to imply that the mineralization must proceed with considerable rapidity, for stems of a soft and succulent character, and of a most perishable nature, are preserved in flint; and there are instances of the complete silicification of the young leaves of a palm-tree when just about to shoot forth, and in that state which in the West Indies is called the cabbage of the palm.[43-A] It may, however, be questioned whether in such cases there may not have been some antiseptic quality in the water which retarded putrefaction, so that the soft parts of the buried substance may have remained for a long time without disintegration, like the flesh of bodies imbedded in peat.
Mr. Stokes has pointed out examples of petrifactions in which the more perishable, and others where the more durable portions of wood are preserved. These variations, he suggests, must doubtless have depended on the time when the lapidifying mineral was introduced. Thus, in certain silicified stems of palm-trees, the cellular tissue, that most destructible part, is in good condition, while all signs of the hard woody fibre have disappeared, the spaces once occupied by it being hollow or filled with agate. Here, petrifaction must have commenced soon after the wood was exposed to the action of moisture, and the supply of mineral matter must then have failed, or the water must have become too much diluted before the woody fibre decayed. But when this fibre is alone discoverable, we must suppose that an interval of time elapsed before the commencement of lapidification, during which the cellular tissue was obliterated. When both structures, namely, the cellular and the woody fibre, are preserved, the process must have commenced at an early period, and continued without interruption till it was completed throughout.[43-B]