[46] Nitrous gas, holding in solution nitrous acid, is more readily absorbed by water than when in its pure form, from being presented to it in a more condensed state in the green acid, formed by the contact of water and nitrous vapor.
[47] Mem. des Savans Etrangers, v. xi. 226. Vide Kirwan sur le phlogistique pag. 110.
[48] In this experiment, as well as in the last, some of the mixture was thrown into the jar undecompounded.
[49] To detach the potash from the carbonic acid.
[50] This nitrogene contained a little nitrous gas, as it gave red fumes when exposed to the air. The free nitrous acid was decomposed by the mercury, as it was not covered with water.
[51] Essay on phlogiston.
[52] Dr. Priestley says, “Having filled a phial containing exactly the quantity of four pennyweights of water, with strong, pale, yellow spirit of nitre, with its mouth quite close to the top of a large receiver standing in water, I carefully drew out almost all the common air, and then filled it with nitrous air; and as this was absorbed, I kept putting in more and more, till in less than two days it had completely absorbed 130 ounce measures. Presently after this process began, the surface of the acid assumed a deep orange color, and when 20 or 30 ounce measures of air were absorbed, it became green at the top: this green descended lower and lower, till it reached the bottom of the phial. Towards the end of the process, the evaporation was perceived to be very great, and when I took it out, the quantity was found to have diminished to one half. Also it had become, by means of this process, and the evaporation together, exceeding weak, and was rather blue than green.”
Experiments and Observations, vol. 1, p. 384. Last edition.
[53] See Mr. Keir’s excellent observations on this subject. Chem. Dict. Art. Acid.
[54] Irish Transactions, vol. 4, p. 34.