As charcoal burns vividly in nitrous gas, when it has been previously ignited to whiteness, I introduced it into a mixture of equal parts of nitrous oxide and nitrous gas; it burnt with a deep and bright red.
IX. Decomposition of Nitrous Oxide
by Hydrocarbonate.
Nitrous oxide, and hydrocarbonate, possess no action on each other, except at high temperatures. When mingled in certain proportions, and exposed to the electric shock, a new arrangement of their principles takes place.
E. 1. Temperature being 53°, 35 of nitrous oxide, mingled with 15 of hydrocarbonate, were fired by the electric spark; the inflammation was very vivid, and the light produced, bright red. After the explosion, the space occupied by the gases equalled about 60. On the admission of solution of strontian, a copious white precipitate was produced, and the gas diminished by agitation, to rather more than 35. When 36 of nitrous gas were added to these, white fumes appeared and the whole diminished to 62. When a little muriatic acid was poured on the white precipitate from the solution of strontian, gas was evolved from it, and it was gradually dissolved.
E. 2. 22 nitrous oxide were inflamed with 20 hydrocarbonate; after the explosion, they filled a space equal to 45; when strontian lime water was introduced, white precipitation took place, and the diminution was to 31.
To these 31, 14 of nitrous oxide were admitted, and the electric spark passed through them; an inflammation took place: carbonic acid was formed, after the absorption of which, the gas remaining filled a space equal to 43, and did not diminish with nitrous gas.
The hydrocarbonate employed in these experiments, was procured from alcohol by means of sulphuric acid. In another set of experiments made with less accuracy, the same general results were obtained. Whenever hydrocarbonate inflamed with nitrous oxide, both its constituents were oxygenated; in all cases carbonic acid was formed, and in no instance free hydrogene evolved, or charcoal precipitated.
In the decomposition of nitrous oxide by hydrocarbonate, the residual nitrogene is less than in other combustions. This circumstance I am unable to explain.
Reasoning from analogy, there can be little doubt, but that when hydrocarbonate is inflamed with excess of nitrous oxide, it will be only partially decompounded, or converted into nitrogene, nitrous acid, and atmospheric air.
The Dutch Chemists have asserted, that charcoal does not burn in nitrous oxide, except in consequence of the previous decomposition of the gas by the hydrogene always contained in this substance; and likewise, that when hydrocarbonate and nitrous oxide were mingled together, and fired by the electric spark, the hydrogene only was burnt, whilst the charcoal was precipitated.