The quantity of graphite in the Lower Laurentian series is enormous. Some years ago, in the township of Buckingham, on the Ottawa River, I examined a band of limestone believed to be a continuation of that described by Sir W. E. Logan as the Green Lake limestone. It was estimated to amount, with some thin interstratified bands of gneiss, to a thickness of six hundred feet or more, and was found to be filled with disseminated crystals of graphite and veins of the mineral to such an extent as to constitute in some places one-fourth of the whole; and, making every allowance for the poorer portions, this band cannot contain in all a less vertical thickness of pure graphite than from twenty to thirty feet. In the adjoining township of Lochaber Sir W. E. Logan notices a band from twenty-five to thirty feet thick, reticulated with graphite veins to such an extent as to be mined with profit for the mineral. At another place in the same district a bed of graphite from ten to twelve feet thick, and yielding 20 per cent, of the pure material, is worked. As it appears in the excavation made by the quarrymen, it resembled a bed of coal; and a block from this bed, about four feet thick, was a prominent object in the Canadian department of the Colonial Exhibition of 1886. When it is considered that graphite occurs in similar abundance at several other horizons, in beds of limestone which have been ascertained by Sir W. E. Logan to have an aggregate thickness of thirty-five hundred feet, it is scarcely an exaggeration to maintain that the quantity of carbon in the Laurentian is equal to that in similar areas of the Carboniferous system. It is also to be observed that an immense area in Canada appears to be occupied by these graphitic and Eozoon limestones, and that rich graphitic deposits exist in the continuation of this system in the State of New York, while in rocks believed to be of this age near St. John, New Brunswick, there is a very thick bed of graphitic limestone, and associated with it three regular beds of graphite, having an aggregate thickness of about five feet.[D]
[D] Matthew in “Quarterly Journal of the Geological Society,” vol. xxi., p. 423. “Acadian Geology,” p. 662.
It may fairly be assumed that in the present world, and in those geological periods with whose organic remains we are more familiar than with those of the Laurentian, there is no other source of unoxidized carbon in rocks than that furnished by organic matter, and that this has obtained its carbon in all cases, in the first instance, from the deoxidation of carbonic acid by living plants. No other source of carbon can, I believe, be imagined in the Laurentian period. We may, however, suppose either that the graphitic matter of the Laurentian has been accumulated in beds like those of coal, or that it has consisted of diffused bituminous matter similar to that in more modern bituminous shales and bituminous and oil-bearing limestones. The beds of graphite near St. John, some of those in the gneiss at Ticonderoga in New York, and at Lochaber and Buckingham, and elsewhere in Canada, are so pure and regular that one might fairly compare them with the graphitic coal of Rhode Island. These instances, however, are exceptional, and the greater part of the disseminated and vein graphite might rather be likened in its mode of occurrence to the bituminous matter in bituminous shales and limestones.
We may compare the disseminated graphite to that which we find in those districts of Canada in which Silurian and Devonian bituminous shales and limestones have been metamorphosed and converted into graphitic rocks not very dissimilar to those in the less altered portions of the Laurentian.[E] In like manner it seems probable that the numerous reticulating veins of graphite may have been formed by the segregation of bituminous matter into fissures and planes of least resistance, in the manner in which such veins occur in modern bituminous limestones and shales. Such bituminous veins occur in the Lower Carboniferous limestone and shale of Dorchester and Hillsborough, New Brunswick, with an arrangement very similar to that of the veins of graphite; and in the Quebec rocks of Point Levi, veins attaining to a thickness of more than a foot, are filled with a coaly matter having a transverse columnar structure, and regarded by Logan and Hunt as an altered bitumen. These palæozoic analogies would lead us to infer that the larger part of the Laurentian graphite falls under the second class of deposits above mentioned, and that, if of vegetable origin, the organic matter must have been thoroughly disintegrated and bituminised before it was changed into graphite. This would also give a probability that the vegetation implied was aquatic, or at least that it was accumulated under water.
[E] Granby, Melbourne, Owl’s Head, &c., “Geology of Canada,” 1863, p. 599.
Dr. Hunt has, however, observed an indication of terrestrial vegetation, or at least of subaërial decay, in the great beds of Laurentian iron-ore. These, if formed in the same manner as more modern deposits of this kind, would imply the reducing and solvent action of substances produced in the decay of plants. In this case such great ore-beds as that of Hull, on the Ottawa, seventy feet thick, or that near Newborough, two hundred feet thick,[F] must represent a corresponding quantity of vegetable matter which has totally disappeared. It may be added that similar demands on vegetable matter as a deoxidising agent are made by the beds and veins of metallic sulphides of the Laurentian, though some of the latter are no doubt of later date than the Laurentian rocks themselves.
[F] “Geology of Canada,” 1863.
It would be very desirable to confirm such conclusions as those above deduced by the evidence of actual microscopic structure. It is to be observed, however, that when, in more modern sediments, Algæ have been converted into bituminous matter, we cannot ordinarily obtain any structural evidence of the origin of such bitumen, and in the graphitic slates and limestones derived from the metamorphosis of such rocks no organic structure remains. It is true that, in certain bituminous shales and limestones of the Silurian system, shreds of organic tissue can sometimes be detected, and in some cases, as in the Lower Silurian limestone of the La Cloche Mountains in Canada, the pores of brachiopodous shells and the cells of corals have been penetrated by black bituminous matter, forming what may be regarded as natural injections, sometimes of much beauty. In correspondence with this, while in some Laurentian graphitic rocks, as, for instance, in the compact graphite of Clarendon, the carbon presents a curdled appearance due to segregation, and precisely similar to that of the bitumen in more modern bituminous rocks, I can detect in the graphitic limestones occasional fibrous structures which may be remains of plants, and in some specimens vermicular lines, which I believe to be tubes of Eozoon penetrated by matter once bituminous, but now in the state of graphite.