| [Captain Generalship of Caraccas], Boundaries and Extent | Page 1 |
| | [Political and Territorial Divisions, Government] | 2 |
| [Discovery, History] | 2 |
| [Capital] | 4 |
| [Description of the Features, &c. of the Country] | 8 |
| [Province of New Andalusia] | 18 |
| —— [New Barcelona] | 18 |
| [Features, Climate, &c.] | 25 |
| [Province of Venezuela and Coro] | 43 |
| —— [Maracaybo] | 58 |
| —— [Varinas] | 65 |
| —— [Spanish Guiana] | 69 |
| [Government of the Island of Margarita] | 73 |
| |
| [Viceroyalty of Peru] | 75 |
| [Extent and Boundaries] | 75 |
| [Political and Territorial Divisions, Government, &c.] | 76 |
| [Discovery, History, &c.] | 83 |
| [Intendancy of Truxillo] | 120 |
| —— [Tarma] | 126 |
| —— [Lima] | 130 |
| —— [Guancavelica] | 134 |
| [Intendancy of Guamanga] | 138 |
| —— [Cuzco] | 140 |
| —— [Arequipa] | 147 |
| |
| [Viceroyalty of Buenos Ayres or La Plata], Boundaries and Extent | 155 |
| [Political and Territorial Divisions, Government, History, Discovery, &c.] | 156 |
| [Features, Climate, &c.] | 161 |
| [Commerce and Resources] | 167 |
| [Government of Los Charcas or Potosi] | 171 |
| —— [Paraguay] | 195 |
| [History, Discovery, &c.] | 195 |
| —— [Tucuman] | 204 |
| —— [Cuyo or Cujo] | 215 |
| —— [Buenos Ayres] | 220 |
| [History, &c]. | 220 |
| [Climate, Features, &c.] | 222 |
| |
| [Captain Generalship of Chili] | 230 |
| [Extent and Boundaries] | 230 |
| [Political and Territorial Divisions and Government] | 231 |
| [Discovery, and History] | 231 |
| [Climate, Features, &c.] | 245 |
| [Population] | 253 |
| [Animals] | 253 |
| [Continental Provinces of Chili] | 264 |
| [Province of Copiapo] | 265 |
| —— [Coquimbo] | 265 |
| —— [Quillota] | 267 |
| —— [Aconcagua] | 269 |
| —— [Melipilla] | 270 |
| —— [Santiago] | 271 |
| —— [Rancagua] | 272 |
| —— [Colchagua] | 273 |
| ——[ Maule] | 274 |
| —— [Itata] | 276 |
| —— [Chillan] | 276 |
| —— [Puchacay] | 277 |
| —— [Huilquilemu] | 279 |
| |
| [Insular Chili] | 282 |
| [Archipelago of Chiloe] | 283 |
| [Araucania or Indian Chili] | 287 |
| [Islands on the Coasts of Spanish South America] | 294 |
| [Plate and Description of comparative Altitudes of the Mountains] | 301 |
| [List of Works on or relating to Spanish America], quoted in this publication, &c. | 305 |
| [Table of the Latitudes and Longitudes of the principal Place]s | 311 |
| [Summary of the Population] | 319 |
| [Wealth and Revenue] | 320 |
| [Index] | 321 |