Besides these there are five convents, each of which has a handsome church, two nunneries, an university, and two colleges.

The greatest evil attending the situation of this city is the want of water, which is only scantily supplied by the public fountains, dispersed in different places.

Chuquisaca is famous as being the seat of the Royal Audience of Los Charcas, which is the supreme court of Buenos Ayres, and has the viceroy for its president; it was erected in 1559.

The magistracy of this city are chosen from among the first nobility, and consist of a corregidor, regidores, and alcaldes, who govern the district attached to the town, which includes a very large space around it, and contains, amongst others, the celebrated city and mines of Potosi.

The inhabitants of La Plata are computed at 14,000.

In the district surrounding the capital, and which is called Charcas, are several rivers, which form from their united streams the Pilcomayo. The names of these rivers are the Tarapaya, that runs from Porco; the Potosi, which is employed in washing the ores in the mines of that name; and the Cachimayo, which passes near La Plata; after the junction of this last, the united stream flows through the districts of Pilaya, Paspaya, and Tomina, from whence it enters Chaco, and runs 80 leagues as far as the Llanos de Manso, after which its channel is through thick forests to the south-east, and it enters the Paraguay, south of the city of Asuncion, in between 25° 40' and 26° 20' south latitude, by two mouths, after a course of 600 miles. Its banks are inhabited by independent nations, who are so warlike, that the Jesuits in vain sought for a passage by this stream, from Peru to Paraguay.

The city of Potosi, included in this jurisdiction, is in 19° 47' south latitude, and 67° 22' west longitude, east-south-east of Lima in Peru, in a country inclosed by the mountainous district of Porco; the climate is cold, and the environs very barren, the valleys being destitute of wood, the sides of the hills covered only with moss, and their summits capped with eternal snows. A few vicunas are now and then seen grazing in this elevated and desolate region, which would never have been frequented by man, had it not happened, that Diego Hualca, an Indian peasant, was pursuing some wild goats, and arriving at a very steep place, laid hold of a small shrub to prevent himself from falling, but the shrub being unable to support his weight, was torn up by the roots, and disclosed to the astonished hunter, a rich mass of silver, lumps of which adhered to the earth, that came away with the plant. The Indian who lived at Porco, made use of this inexhaustible fund of riches for a length of time, but his good fortune could not remain long concealed, as his friend Guanca, observing a considerable change in his manner of living, became anxious to investigate the cause, and pressing Hualca constantly to know the reason, he at last disclosed the mystery. They however kept their secret for some time, till Hualca, refusing to show his friend the manner of purifying the metal, the latter related the whole affair to Villaroel, his master, who also resided at Porco. Villaroel accordingly proceeded to the vein, on the 21st of April 1545, and procuring the necessary assistance, the mine was immediately opened.

The city of Potosi was founded in a narrow glen, on the river of the same name, on the south side of the mountain which contains the mines, in the year 1547. A royal mint was established in 1562, and so rapidly did its population increase, that in 1611, the town contained 160,000 inhabitants, but from various causes, the population of this city since that time has continually decreased, and at present it consists only of about 30,000 souls. Potosi has a mint, six convents, two nunneries, a college and an hospital; and its inhabitants are still chiefly concerned in the working of the mines, and consist of whites, mestizoes, and Indians, for the latter of whom there are six curates and chapels in the city and its district. The city of Potosi is 45 miles west-south-west of La Plata.

The celebrated mines of Potosi are in the same mountain on which the city is built. This mountain is three miles in circumference, and is of a sharp conical figure, rising to the height of 4360 feet above the plain, and is known by the name of Hatun Potocsi; its summit is crowned by a bed of porphyry, which gives it the well defined conical form it possesses. This famous mine has caused the destruction of thousands of human beings, for in the latter end of the 16th century, 15,000 Indians were constantly forced to work in it; but at present, there are not more than 2000 miners, who are well paid, and usually work from choice alone; 15,000 llamas and 15,000 asses, are constantly employed in carrying the ore to the amalgamation works in the city. The mint of Potosi coined in 1790, 299,246 piastres of gold, and 3,293,173 of silver, or 886,620l. sterling. From the discovery of these mines, till the year 1803, they have supplied 1,095,500,000 piastres, or 237,358,334l. sterling, which has paid the royal duties; and this also only includes silver, consequently the gold and smuggled metals must have swelled the total furnished by the works to a much greater amount. At present, the minerals are poor, and their abundance only causes the Spaniards to work them; but according to Helms, if they were properly managed, they would still produce from twenty to thirty millions of dollars yearly. The mountain is perforated by about 300 rude shafts; and the numerous furnaces which surround it, form at night a very singular spectacle. Potosi is distant from its metropolis, Buenos Ayres, 1873 miles across a road, which for 400 miles, lies over a rocky mountainous country, very difficult to pass.