It is to be noticed that fluorine is the only member of the halogen family which occurs in nature in combination with rare earth elements. This fact is possibly connected with the great age of the rare earth minerals, and their formation during pneumatolytic metamorphism of plutonic rocks (vide [Chapter I]).
CHAPTER VII
THE MONAZITE SANDS
It has been stated that monazite is a not uncommon accessory constituent of many rocks, particularly of granites, gneisses, diorites, etc. The crystalline material, of which an account has been given, is found sometimes in veins in these rocks, more often in tiny crystals disseminated throughout the mass. Most of these monazite-bearing rocks are extremely old, belonging to the Archæan or pre-Cambrian age, and probably none are of secondary (Mesozoic) or later age. It follows, then, that they have been subjected to erosion during practically the whole immense period of which geology can give us any detailed knowledge. Heat, frost, wind, the action of vegetation and of percolating water, the innumerable weathering agents known to the geologist, have been at work on them during countless ages, breaking, crushing, dissolving; rains, brooks, rivers, even ocean-waves have dissolved or washed away the fragments, sorted them out unerringly according to density, and re-deposited them, now in a river-bed, now at the base of some sea cliff, now in a wide alluvial plain from which the water has long since retired. It is in deposits of this nature that the monazite has been concentrated. Its relatively high specific gravity (about 5·0) has secured its separation from the lighter mica, quartz, and felspar of the parent-rock; but the heavier vein or accessory minerals have, of course, been concentrated with it. Zircon is an invariable constituent of these ‘monazite sands,’ as such deposits are called; and others almost as frequently found are rutile, ilmenite, sphene (titanite), and apatite. Common, too, are the characteristic minerals of the metamorphic rocks, garnet, epidote, sillimanite, tourmaline, etc. Rare earth minerals found in the monazite sands include xenotime, fergusonite, samarskite, gadolinite, and allanite. The remaining minerals are oxides of iron and tin, with, of course, a considerable amount of quartz.
It is apparent, from what has been said above, that monazite will be concentrated with the heaviest constituents of the rocks from which it is derived. Very often, indeed usually, these rocks are precisely those in which gold occurs, disseminated sometimes in tiny particles, sometimes collected into nuggets in veins of quartz and pegmatitic minerals. The erosion of these rocks concentrates the gold with the heaviest minerals; and hence it happens that monazite is an almost universal constituent of the gold- and gem-bearing sands and gravels. In the Carolinas and in Brazil, monazite is found in the gold washings; and though in the past the two have always been extracted separately, the gold first and the monazite from the washings or tailings, there appears to be no reason why a system calculated to extract both—where, of course, the content is high enough—should not be put into operation in the future.
A chemical test affords the only reliable method of detecting monazite in a sand. A little of the sand is washed with water to remove the lighter minerals and warmed with concentrated sulphuric acid. A few drops of the liquid are poured off, evaporated to small bulk, and one drop placed on a glass plate. This is placed under a microscope and one drop of a concentrated solution of sodium acetate is added. If monazite is present in the sand, tiny pointed oval crystals of sodium cerium sulphate will separate.
On the commercial scale, monazite is extracted from the sands only, in the manner described below. An effort was made in North Carolina in 1906 by the British Monazite Company, representing the South Metropolitan Gas Light Company of London, to extract monazite from the rock in which it occurs disseminated. The rock was crushed and powdered, and the monazite separated by washing off the lighter particles on concentration tables (see [below]). In the same year, however, the price of thorium nitrate was suddenly lowered 50 per cent. by the German Thorium Syndicate, which largely controls the Brazilian output of monazite, and the British company stopped operations in 1907. At present it may be said that only the sands are available for profitable extraction.
Up to 1895, the Carolina deposits, which were worked chiefly by the Welsbach Light Company of New York, either directly or indirectly, supplied all the demand, but in that year the Brazilian sands were first worked, and a keen struggle commenced for the market. The American companies, after keeping up a considerable output for some years, were forced to suspend operations in May 1910. The Brazil deposits, worked by the German Thorium Syndicate and the Austrian Welsbach Company, which have an agreement, now meet practically the whole demand. The Brazilian sand occurs chiefly along the shores of the southern provinces, having been concentrated by the action of the tides from the products of erosion of the cliffs; it is very uniform and considerably richer than the Carolina sand, and owing to its occurrence on the sea-shore, the cost of transporting it is very low. It is exported chiefly to Germany, recently also to the United States, and to a small extent lately to England. The method of working it is similar to that employed in Carolina—namely, concentration by washing and magnetic separation.
The North American Deposits[119]
[119] See Nitze, Bull. No. 9, N. Carolina Geol. Survey, 1895; also Test, Colorado School of Mines Bull. Vol. IV. No. 2, p. 125, Jan. 1908.