[257] Brauner, Monats. 1882, 3, 1; Marc, Ber. 1902, 35, 2370; Meyer and Koss, ibid. 3470.
When heated in a stream of hydrogen, the dioxide yields the sesquioxide, Pr₂O₃, as a greenish-yellow powder,which readily absorbs oxygen from the air, becoming brown, with formation of the intermediate oxide.
The chloride, PrCl₃,7H₂O, forms large green prisms, very readily soluble in water; 100 parts of the solvent at 13° take up 334·2 parts of the hydrated salt, the solution having the specific gravity 1·687. The anhydrous chloride is a pale green deliquescent powder, which melts at a red heat to a clear green liquid; ebullioscopic measurements show that in alcoholic solution it has the simple molecular formula PrCl₃.
The Bromate, Pr(BrO₃)₃,9H₂O, has been obtained by James and Langelier[258] by dissolving the oxide in aqueous bromic acid, and also by double decomposition. It forms greenish hexagonal prisms, melting at 56·5°, and is readily soluble; 100 parts of water dissolve 190 parts of this salt at 25°. At 100° it loses five molecules of water, forming the tetrahydrate Pr(BrO₃)₃,4H₂O, which loses all its water at 130°. The anhydrous salt begins to decompose at 150°.
[258] J. Amer. Chem. Soc. 1909, 31, 913.
The sulphate crystallises with 8 molecules of water of crystallisation at ordinary temperatures, but hydrates with 151⁄2, 12, and 5 molecules of water respectively have been described. The octohydrate is considerably more soluble than lanthanum sulphate enneahydrate. The anhydrous salt is a bright green powder.
Praseodymium acetylacetone melts at 146°.
Atomic Weight.
—The value 140·6, adopted by the International Committee, is based on the work of Jones, v. Scheele, Auer von Welsbach, and Feit and Przibylla; the work of Brauner, however, points consistently to a higher atomic weight. Most of these investigators have used the sulphate method. The first determinations of von Welsbach for the newly discovered element[259] gave the value 140·8 (see [p. 179]); another series of determinations published in 1903[260] gave the mean value 140·57. Jones[261] obtained the sesquioxide for the synthetic sulphate operation by reduction of the peroxide in a current of hydrogen; according to Brauner, this method gives an oxide which is not perfectly pure, probably by absorption of water vapour and carbon dioxide from the air. Jones’ mean value was 140·466. v. Scheele[262] used the same method, as well as a combined oxalate-sulphate method; his figures vary considerably, the mean value being 140·55. Feit and Przibylla,[263] using their volumetric method, obtained the value 140·54.
[259] Monats. 1885, 6, 477.