Colloidal solutions possess only a very feeble osmotic pressure. The lowering of the freezing point and the other corresponding constants are also quite insignificant. This arises from the fact that the molecules of a colloid are extremely large when compared with those of a crystalloid. For example let us take colloidal substance whose molecular weight is 2000. A solution containing 40 grammes per litre would have an osmotic pressure only one-fiftieth of that of a
solution of similar strength of a crystalloid whose molecular weight was 40.
Not only so, but on measuring the molecular concentration, the osmotic pressure, and the other constants of a colloidal solution, we find values even lower than those which we should expect from a consideration of its molecular weight. This is probably due to the tendency of a colloid to polymerization, i.e. to form groups or associations of molecules. Suppose, for instance, that the molecules of a colloidal solution are aggregated into groups of ten. Since each group plays the part of a simple molecule, the osmotic pressure will be ten times less than that corresponding to the quantity of the solute present. Such a group of molecules is called by Naegeli a "micella."
Similar phenomena of aggregation may be observed in the molecules of many inorganic substances. The molecule of iodine, for example, is monatomic at 1200° C., but becomes diatomic at the ordinary temperature. Sulphur at 860° C. is a gas with a vapour density of 2.2, while at 500° C. its vapour density rises to 6.6. In both of these cases two or more molecules of the element have been condensed into one as a result of the fall of temperature.
We frequently find that two successive cryoscopic observations on the freezing point of the same colloidal solution will vary. This is due to the extreme sensitiveness of the micellæ, which absorb or abandon their extra molecules under the slightest influence. This mobility in the constitution of the micellæ appears to be one of the principal causes of the peculiar properties of colloidal solutions.
The phenomenon of polymerization appears to be reversible. The micellæ are formed under certain conditions, and are disintegrated when these conditions are removed. The osmotic pressure varies in the same manner, diminishing with polymerization and augmenting with the disintegration of the micellæ. One may easily understand what an important rôle is played by this alternate polymerization and disintegration in the phenomena of life.
Most colloidal substances are precipitated from their solutions by the addition of very small quantities of electrolytic
solutions. Non-electrolytic solutions do not appear to provoke this precipitation. This is not a chemical action, for an exceedingly small quantity of an electrolyte is able to precipitate an indefinite quantity of the colloid. The precipitation is probably due to the electric charges carried by the dissociated ions of the electrolytes.
When an electric current is passed through a colloid solution, the course of the molecules of the colloid is sometimes towards the cathode and sometimes towards the anode, according to the nature of the colloid and of the solvent. This displacement would appear to indicate a difference of electric potential between the molecules of the colloid and those of the solvent. Hardy has shown that in an alkaline solution the molecules of albumin travel towards the anode, while in an acid solution they travel towards the cathode.
Metallic Colloids.—Carey Lea and afterwards Credé succeeded in obtaining silver in colloidal solution by ordinary chemical means. Professor Bredig has introduced a more general method of obtaining a number of metals in colloidal solutions in a state of great purity. He causes an electric arc to pass between two rods of the metal immersed in distilled water. The cathode is thus pulverized into a very fine powder which rests in suspension in the liquid, constituting a colloidal solution. Bredig has in this way prepared sols of platinum, palladium, iridium, silver, and cadmium.