So in other departments of science—a factor which is almost infinitesimal may yet exercise a vast influence on the results. It is by infinitesimal variations of pressure, a thousandth of a millimetre or less, that we obtain the various degrees of penetration in the Röntgen rays.
The division into solutions and pseudo-solutions or suspensions is also an arbitrary one. A true solution is also a suspension of the molecules of the solute. There is no essential difference between a solution and a suspension, but only a difference in the size of the molecules, or agglomerations of molecules, in one case so small as to be transparent, and in the other case just big enough to diffuse light. There are moreover many properties common to colloidal solutions and suspensions of fine powders, such as kaolin, mastic, charcoal, or Indian ink. These particles in suspension are precipitated by solutions of electrolytes in a manner similar to the coagulation of colloids.
The surface of every liquid is covered by a very thin layer, a sort of membrane slightly differentiated from the rest of the liquid. This membrane may be a chemical one, a pellicular precipitate like that which is formed by the contact of two membranogenous liquids. On the other hand, the membrane may not differ from the subjacent liquid in chemical composition, but only in physical properties. If we
consider the molecules in the middle of a liquid, each molecule is subjected to the cohesive attraction of molecules on every side, attractions which neutralize one another. At the surface of the liquid, however, there are quite other conditions of equilibrium. There each molecule is drawn downwards towards the centre of the liquid, and there is no compensating attraction in an opposite direction. The resultant pressure is normal to the surface of the liquid, and is mechanically equivalent to an elastic membrane which tends to diminish the surface, and hence the volume of the liquid. We may therefore regard this surface tension as acting the part of a veritable physical membrane.
There is a still further differentiation of the surface of a liquid. When the liquid is not a simple one, but complex as in a solution, we find that the concentration of the solute is greater at the surface than in the interior. This is the so-called phenomenon of "adsorption," which is another cause for the production of a physical membrane covering the surface of a liquid.
Substances in a colloidal state have a great tendency to form these chemical or physical membranes at the point of contact between the colloidal solute and the solvent. This is probably the reason why the coagulum of a colloidal liquid usually presents a vacuolar or spongy structure.
CHAPTER V
DIFFUSION AND OSMOSIS