Pearls and mother-of-pearl both owe their iridescence to a similar ruled structure, which is developed in the living tissue of a mollusc. They are, in fact, periodic precipitates of phosphate and carbonate of lime deposited in the colloidal organic substance of the mollusc. They have the same structure and the same chemical composition; they have the same physical properties, the glow, the fire, and the brilliancy of our spectroscopic gratings. In these experiments, indeed, we have realized the synthesis of the pearl, not only a chemical synthesis, but the synthesis of its structure and organism.
We have been able to make these periodic precipitates by the reaction of a great number of chemical substances, giving a bewildering variety of form and structure. Some of these recall the form of various organisms, and especially of insects, as may be seen in Fig. 18.
All the phenomena of life are periodic. The movement of heart and lungs, sleep and waking, all nervous phenomena, have a regular periodicity. It is possible that the study of these purely physical phenomena of periodic precipitation may give us the key to the causation of rhythm and periodicity in living beings.
Besides this periodic precipitation there appear to be other chemical reactions which are periodic. Professor Bredig of Heidelberg has lately described a curious phenomenon, the
periodic catalysis of peroxide of hydrogen by mercury. He thus describes his experiment: "We place in a perfectly clean test tube a few cubic centimetres of perfectly pure mercury. Upon this we pour 10 c.c. of a 10 per cent. solution of hydrogen peroxide. The mercury speedily becomes covered with a thin, brilliant bronze-coloured pellicle which reflects light. Then little by little catalysis of the hydrogen peroxide begins, with liberation of oxygen. After some time, from five to twenty minutes, the liberation of gas at the surface of the mercury ceases, the cloud formed by the gas bubbles disappears, and the bronze mirror at the surface of the mercury lights up with the glint of silver. There is a pause of one or more seconds, and then the catalytic action begins afresh, commencing at the edges of the mirror. The cloud is again formed and again disappears. This beautiful and surprising rhythmic phenomenon may continue at regular intervals for an hour or more."
A slight alkalinity of the liquid is necessary to start the phenomenon. This explains the retardation at the beginning
of the experiment, since the rhythmic catalysis cannot begin until the hydrogen peroxide has dissolved a little of the glass so as to render it slightly alkaline. The catalytic process may, however, be set going at once by adding a trace of potassium acetate to the solution.
We may even obtain a curve giving an automatic record of the periodicity of this catalytic action. For this purpose the oxygen given off is led to a manometer, which registers on a revolving drum the periodic variation in pressure. The curve thus obtained presents a remarkable resemblance to a tracing of the pulse. The frequency and character of the undulatory curve is modified by physical and chemical influences. Like circulation or respiration, periodic catalysis has its poisons, and exhibits signs of fatigue, and of paralysis by cold.
The rhythmic catalysis of Bredig produces an electrical current of action between the mercury and the water just like that produced by the rhythmic contraction of the heart, and this current may be registered in a similar way by means of the Einthoven galvanometer. Thus the heart-beat may be but an instance of rhythmic catalysis, since both produce the same phenomena, movement, chemical action, and periodic currents. In the chapter on physiogenesis we shall return to the study of this question and consider another rhythmic phenomenon which is the result of osmotic growth.