In the early spring or summer, when the light is powerful, probably about ten to fifteen minutes will be required; but from three-quarters of an hour to an hour and a half may be allowed in the winter months, even in the direct rays of the sun.
It is always easy to judge of the length of time which will be sufficient, by exposing a small slip of the sensitive paper, unshielded, to the sun's rays, and observing how long it takes to reach the coppery stage of reduction. Whatever that time may be, nearly the same will be occupied in the printing, if the Negative be a good one.
When the darkening of the paper appears to have proceeded to a considerable extent, the frame is to be taken in and the picture examined. If squares of plate glass are used to keep the Negative and sensitive paper in contact, some difficulty may be experienced at first in returning it precisely to its former position after the examination is complete, but this will easily be overcome by practice. The finger and thumb should be fixed on the lower corners or edge, and the plate raised evenly and quickly.
If the exposure to light has been sufficiently long, the print appears slightly darker than it is intended to remain. The toning Bath dissolves away the lighter shades, and reduces the intensity, for which allowance is made in the exposure to light. A little experience soon teaches what is the proper point; but much will depend upon the state of the toning Bath; and albuminized paper will require to be printed somewhat more deeply than plain paper.
If, on removal from the printing-frame, a peculiar spotted appearance is seen, produced by unequal darkening of the Chloride of Silver, either the Nitrate Bath is too weak, the sheet removed from its surface too speedily, or the paper is of inferior quality.
On the other hand, if the general aspect of the print is a rich chocolate-brown in the case of Albumen, a dark slate-blue with Ammonio-Nitrate Paper, or a reddish purple with paper prepared with Chloride and Citrate of Silver, probably the subsequent parts of the process will proceed well.
If, in the exposure to light, the shadows of the proof become very decidedly coppery before the lights are sufficiently printed, the Negative is in fault. Ammonio-Nitrate paper highly salted is particularly liable to this fault of excess of reduction, and especially so if the light be powerful; hence it is best, in the summer months, not to print by the direct rays of the Sun. This point is important also, because the excessive heat of the Sun's rays often cracks the glasses by unequal expansion, and glues the Negative firmly down to the sensitive paper. An exception however may be made in the case of Negatives of great intensity; which are printed most successfully upon, a weakly sensitized paper ([p. 124]) exposed to the full rays of the Sun; a feeble light not fully penetrating the dark parts.
The fixing and toning of the proof.—No injury results from postponing this part of the process for many hours, provided the print be kept in a dark place.
The mode often followed is to immerse the Positive in the Hyposulphite Bath in the state in which it comes from the printing-frame; moving it about in the liquid in order to displace air-bubbles, which, if allowed to remain, produce spots. But the Author, for reasons given in the first part of the Work (pp. [129] and [165]), recommends that the print should first be washed in common water until the soluble Nitrate of Silver has been removed.[47] This is known to be the case when the liquid flows away clear; the first milkiness being caused by the soluble Carbonates and Chlorides in the water precipitating the Nitrate of Silver. Greater security is thus afforded that the print will be toned in a really permanent manner, since after removing the Nitrate of Silver from the proof, the Bath does not work quickly unless the supply of Gold be well maintained.
[47] This water must be free from Hyposulphite of Soda, or the print will become discoloured.