The commercial Glacial Acetic Acid is often diluted with water, which may be suspected if it does not solidify during the cold winter months. Sulphurous and Hydrochloric Acids are also common impurities. They are injurious in Photographic Processes, from their property of precipitating Nitrate of Silver. To detect them proceed as follows:—dissolve a small crystal of Nitrate of Silver in a few drops of water, and add to it about half a drachm of the Glacial Acid; the mixture should remain quite clear even when exposed to the light. Hydrochloric and Sulphurous Acid produce a white deposit of Chloride or Sulphite of Silver; and if Aldehyde or volatile tarry matter be present in the Acetic Acid, the mixture with Nitrate of Silver, although clear at first, becomes discoloured by the action of light.
Glacial Acetic Acid sometimes has a smell of garlic. In this state it probably contains an organic Sulphur Acid, and is unfit for use.
Many employ a cheaper form of Acetic Acid, sold by druggists as "Beaufoy's" acid; it should be of the strength of the Acetic Acid fortiss. of the London Pharmacopœia, containing 30 per cent, real acid. It will be advisable to test it for Sulphuric Acid (see Sulphuric Acid), and other impurities, before use.
ACETATE OF SILVER. See [Silver, Acetate of].
ALBUMEN.
Albumen is an organic principle found both in the animal and vegetable kingdom. Its properties are best studied in the white of egg, which is a very pure form of Albumen.
Albumen is capable of existing in two states; in one of which it is soluble, in the other insoluble, in water. The aqueous solution of the soluble variety gives a slightly alkaline reaction to test-paper; it is somewhat thick and glutinous, but becomes more fluid on the addition of a small quantity of an alkali, such as Potash or Ammonia.
Soluble Albumen may be converted into the insoluble form in the following ways:—
1. By the application of heat.—A moderately strong solution of Albumen becomes opalescent and coagulates on being heated to about 150° Fahrenheit, but a temperature of 212° is required if the liquid is very dilute. A layer of dried Albumen cannot easily be coagulated by the mere application of heat.
2. By addition of strong acids.—Nitric Acid coagulates Albumen perfectly without the aid of heat. Acetic Acid however acts differently, appearing to enter into combination with the Albumen, and forming a compound soluble in warm water acidified by Acetic Acid.