The solution of Nitrate of Silver obtained by dissolving Sulphuret of Silver, is always strongly acid with Nitric Acid, and also contains Sulphate of Silver. It may be crystallized by evaporation; but unless the quantity of material operated on is large, it will be better to precipitate the Silver in the form of Chloride, by adding common Salt, as already recommended.
REDUCTION OF CHLORIDE OF SILVER TO THE METALLIC STATE.
The Chloride of Silver is first to be carefully washed, by filling up the vessel which contains it, many times with water, and pouring off the liquid, or drawing it off close with a siphon. It may then be dried at a gentle heat, and fused with twice its weight of dry Carbonate of Potash, or better still, with a mixture of the Carbonates of Potash and Soda.
The process for reducing Chloride of Silver in the moist way, by metallic Zinc and Sulphuric Acid, is more economical and less troublesome than that just given; it is conducted as follows:—The Chloride, after having been well washed as before, is placed in a large flat dish, and a bar of metallic Zinc laid in contact with it. A small quantity of Oil of Vitriol, diluted with four parts of water, is then added, until a slight effervescence of Hydrogen gas is seen to take place. The vessel is set aside for two or three days, and is not to be disturbed, either by stirring or by moving the bar. The reduction begins with the Chloride immediately in contact with the Zinc, and radiates in all directions. When the whole mass has become of a grey colour, the bar is to be carefully removed and the adhering Silver washed off with a stream of water; the Zinc usually presents a honeycombed appearance, with irregularities upon the surface, which however are not metallic Silver;—they consist only of Zinc or of Oxide of Zinc.
In order to ensure the purity of the Silver, a fresh addition of Sulphuric Acid must be made, after the Zinc bar has been removed, and the digestion continued for several hours, in order to dissolve any fragments of metallic Zinc which may have been inadvertently detached. The grey powder must be repeatedly washed, first with Sulphuric Acid and water (this is necessary to dissolve a portion of an insoluble Salt of Zinc, probably an oxychloride) and then with water alone, until the liquid runs away neutral, and gives no precipitate with Carbonate of Soda; it may then be fused into a button, to burn off organic matter if present, and subsequently converted into Nitrate of Silver by boiling with Nitric Acid diluted with two parts of water.
In reducing Chloride of Silver precipitated from old Nitrate Baths containing Iodide of Silver, the grey metallic powder is sometimes contaminated with unreduced Iodide of Silver, which dissolves in the solution of Nitrate of Silver formed on treating the mass with Nitric Acid. To avoid this, wash the purified Silver with solution of Hyposulphite of Soda, and then again with water.
MODE OF TAKING THE SPECIFIC GRAVITY OF LIQUIDS.
Instruments are sold, termed "Hydrometers," which indicate specific gravity by the extent to which a glass bulb containing air, and properly balanced, rises or sinks, in the liquid; but a more exact process, and one equally simple, is by the use of the specific gravity bottle.
These bottles are made to contain exactly 1000 grains of distilled water, and with each is sold a brass weight, which counterbalances it when filled with pure water.