Calculations have been made which illustrate the quantitative importance of the solution effected by ground-water. The springs of Leuk (Switzerland) bring to the surface annually more than 2000 tons of calcium sulphate (gypsum) in solution, and in the same time the springs of Bath (England) bring up an amount of mineral matter in solution sufficient to make a column 9 feet in diameter, and 140 feet high.[100]
The amount of mineral matter in solution in streams is also significant, for while stream-water is not all derived from ground-water, much of it had such an origin. In the case of several streams, among them the Thames and the Elbe, careful estimates of the amount of dissolved mineral matter have been made. Though the Thames drains an area only about one-tenth as large as the State of New York, it is estimated to carry about 1500 tons of mineral matter in solution to the sea daily.[101]
From the uppermost 20,000 square miles of its drainage basin the Elbe is estimated to carry yearly about 1,370,000 tons of mineral matter in solution. Estimates of the amounts of material carried to the sea in solution by several rivers are given on pp. [102] and [103]. Much of this matter was brought to the rivers by waters which had been underground before reaching the streams.
From these figures it is clear that we have to reckon here with a very considerable factor in the lowering of land surfaces. From the amount of lime carbonate carried by the Thames it has been estimated that the average amount of this material dissolved from the limestone area drained by this stream is 143[102] tons per square mile per year. It is estimated that, on the average, something like one-third as much matter is carried to the sea in solution as in the form of sediment, and that by this process alone land areas would be lowered something like one foot in 13,000 years.[103]
Deposition of mineral matter from solution.—The deposition of material from solution is effected in several ways. (1) It is sometimes deposited by evaporation. This is well shown where water seeps out on arid lands. The same process is illustrated when water is boiled. (2) Reduction of temperature often occasions deposition. In general, hot water is a better solvent of mineral matter than cold,[104] and if it issues with abundant mineral matter in solution the precipitation of some of it is likely to take place. (3) Plants sometimes cause the precipitation of mineral matter from solution. About some hot springs, even where the temperature of the water is very high small plants of low type (algæ) grow in profusion. In ways which are not perfectly understood these algæ extract the mineral matter from the hot water. They are now thought to be a chief factor in the deposits about the hot springs of the Yellowstone Park.[105] The influence of organisms on precipitation from solution is not confined to the waters of hot springs. (4) A fourth factor involved in the deposition of mineral matter from solution is pressure. Pressure increases the solvent power of water with respect to minerals directly; it produces the same effect indirectly by its effect on the solution of gases. As water charged with gas comes to the surface, the pressure is relieved and some of the gas escapes. Such mineral matter as was held in solution by the help of the gas which escapes is then precipitated. (5) Precipitation is also sometimes effected by the mingling of waters containing different mineral substances in solution. Such mingling of solutions would be most common along lines of ready subterranean flow, and while each portion of the water entering a crevice or porous bed may be able to keep its own mineral matter in solution, their mingling may involve chemical changes resulting in the formation of insoluble compounds, and therefore in deposition. This principle has probably been involved in the filling of many fissures and crevices, converting them into veins. (6) The escape of gases from water, whether from increase of temperature or by the disturbance of water, sometimes causes the deposition of mineral matter held in solution.
The deposition of material held in solution is most notable at two zones, one below that of most active solution, and the other at the surface, where evaporation is active. Under proper conditions, however, deposition may take place at any level reached by water.
Mechanical Work.
The mechanical work of ground-water is relatively unimportant. Wherever it is organized into definite streams, the channels through which it flows are likely to be increased by mechanical erosion as well as by solution. Either beneath the surface, or after the streams issue, the mechanical sediment carried will be deposited.
Fig. 202.—Diagram to illustrate the general form and relations of caves developed by solution. The black portions represent the cavern spaces. Some limestone sinks are represented on the surface above.