When a lava is cooled quickly, the commingled silicates solidify in the diffused condition essentially as they were in the liquid; for there is no time for the silicate molecules of a like kind to come together, particle by particle, in regular systematic order, as required in crystallization. The essential feature of crystallization is this systematic arrangement of the molecules according to a definite plan, giving a specific crystal form, as a cube, a hexagonal prism, etc.
There are six (sometimes made seven) fundamental systems of crystallization, and a multitude of variations of special form in each system. The treatment of these forms belongs to mineralogy.
In a thick viscid liquid, this systematic arrangement of molecules into definite crystal forms takes place slowly, for the crystalline force in the silicates is far less energetic than that in water, which crystallizes into ice with much rapidity and with great force. Because of this slowness, the solidification of the lava may catch the process of crystallization at any stage. If the lava is cooled quickly, the result is a glass; if less quickly, part glass and part crystals; if slowly enough, all becomes crystalline. In general the slower the growth the larger the crystals. The solidification product may, therefore, range from a glass to a mass of crystals; i.e., it may be (1) wholly glass, (2) a glassy matrix with a few small crystals scattered through it, (3) a less abundant glassy matrix with more and larger crystals, (4) a mere remnant of glass in a mass of crystals, or (5) a mass of crystals with no glass.
Successive stages of crystallization.—Since eruptions take place intermittently, it is obvious that cooling of the lava may be in progress in its hidden reservoir during the quiescent intervals between eruptions. After a certain stage of partial crystallization has been reached during such time of quiet, a renewal of eruption may take place and the whole mass of lava be shifted into quite new conditions, and a second phase of solidification may be superposed on the one already started. The rock will then show two phases of crystallization: (1) large crystals of the kind or kinds most prone to develop in the given lava may have grown during the first long stage of slow subterranean cooling, while the greater part of the lava still remained liquid; and (2) small crystals or glass may have developed when the more rapid cooling under the new conditions took place. The result would be large crystals set in a matrix of small crystals or of glass, a combination styled porphyritic. In such cases the lava, in its later stages, carries the large crystals floating throughout its mass, and is not a simple liquid.
THE FRAGMENTAL PRODUCTS OF SUDDEN COOLING.
Pyroclastic rocks.—The extreme example of sudden cooling is presented when lavas are violently exploded into the air and solidify almost instantly. The resulting glassy particles or filaments, if small, constitute volcanic ash. The explosion appears to be due to steam and other gases which are held in the deeper lava under great pressure, but which, as they rise toward the surface of the lava where the pressure is relieved, expand with explosive violence. It is probably also due in part to progressive crystallization, which forces the gases out from the part that crystallizes and overcharges the rest. Sometimes the projected particles draw after themselves long filaments like the threads of spun glass, and sometimes while in the air they divide and draw apart, spinning a filament of viscid lava between them. A variety of this kind at the volcano of Kilauea in Hawaii is known as “Pele’s hair.” These light filaments drift with the wind and lodge on the lee side of the volcano, covering the surface “like mown grass” (Dana).
Fig. 336.—Volcanic bomb. About half natural size. (Photo. by Church.)
When the exploded fragments are coarser they fall about the volcanic vent and form the tuffs (tufa) of which most steep volcanic cones are chiefly built. In these larger fragments, crystals are not infrequently found, and the same is even true of the volcanic ash. These crystals are undoubtedly such as had already been formed in the lava before it exploded, and their formation, as suggested above, may have contributed to the explosion.
Fragments too large to be borne far away by the air, but still small, are known as lapilli, especially if they are somewhat rounded and gravel-like. A finer variety, of the nature of sand, much used in making Portland cement, is locally known as puzzolana.