Geology, Vol. 1 [of 3]

by Thomas C. Chamberlin; Rollin D. Salisbury

Precipitation from solution.—The water in the soil is constantly evaporating. Such substances as it contains in solution are deposited where the water evaporates, and where evaporation is long continued without re-solution of the substances deposited, the surface becomes coated with an efflorescence of mineral matter. Conspicuous examples are found in the alkali plains of certain areas in the western part of the United States. Since the alkaline efflorescence is the result of evaporation it is connected with the atmosphere, but the material of the efflorescence was brought to its present position by water. The principle involved is illustrated by the white efflorescence which frequently appears on brick walls during the dry days which follow a drenching rain. The water penetrates the brick and mortar and dissolves something of their substance, and when it is evaporated from the surface the material in solution is left behind.

In arid regions the deposition of substances other than alkali is common. The percolating waters dissolve whatever is soluble, and when they evaporate their mineral content is left. The pebbles and stones of the arid plains have in many places become heavily coated with mineral matter deposited in this way, and not infrequently cemented into conglomerate. One of the commonest mineral substances found in such situations is lime carbonate. In some cases it was doubtless derived by solution from limestone beds beneath the surface, but this is not always the case. It often encrusts the bits of lava on lava plains where it can hardly have been derived from limestone. The faces of cliffs of granite or gneiss, hundreds and even thousands of feet above all other sorts of rock,[19] are sometimes spotted with patches of lime carbonate. In the first case the lime carbonate was derived by chemical change from the lava, and in the second, from the granite or gneiss (see [Carbonation] below), but its present position is the result of evaporation.

Oxidation.—In the presence of moisture the oxygen of the air enters into combination with various elements of the soil and rocks. This is oxidation. No other common mineral substance shows the results of oxidation so quickly and so distinctly as iron. The oxidized portion is loose and friable, and a mass of iron exposed to a moist atmosphere will ultimately crumble away. This change is comparable to other less obvious changes taking place in many minerals at and below the surface. Oxidation generally involves the disintegration of the rock concerned. Its effects in this direction will be referred to in other connections.

Carbonation.—The production of lime carbonate from rock containing calcium compounds, but not in the form of carbonates, is known as carbonation, and is one of the important chemical changes effected by the carbon dioxide of the atmosphere in coöperation with water. In the process of carbonation the original minerals of complex composition are decomposed and simpler ones usually formed. Volumetric changes are involved, which often lead to the disruption of the rock (see Ground water). Furthermore, carbonates are among the more soluble minerals, and their production therefore brings some of the rock materials into a soluble condition, and their extraction through solution tends still further to disintegrate the rock. The carbonation of crystalline rocks is therefore a disintegrating process, and will be considered further in its many concrete applications.

Other chemical changes.—A third chemical process which often accompanies oxidation and carbonation is hydration. This is effected by water rather than by air, and will be considered in that connection. In general it leads to the disintegration of the minerals and rocks affected. The chemical effects of nitric acid, etc., developed through the agency of atmospheric electricity, and the corresponding effects of the gases and vapors which issue from volcanoes, many of them chemically active, are to be mentioned in this connection.

Conditions favorable for chemical changes.—Conditions are not everywhere equally favorable for the chemical work of the atmosphere. In general, high temperatures facilitate chemical action, and, other things being equal, rocks are more readily decomposed by atmospheric action in warm than in cold regions. Chemical activity is probably greater where the climate is continuously warm than where there are great changes of temperature. Changes of temperature, on the other hand, tend to disrupt rock, and thus increase the amount of surface exposed to chemical change. Since nearly all the chemical changes worked by the atmosphere on the rocks are increased by the presence of moisture, the chemical activity of the atmosphere is greater in moist than in dry regions.

B. THE ATMOSPHERE AS A CONDITIONING AGENCY.

The most obvious mechanical work of the atmosphere is effected by the wind, but mechanical results of great importance, conditioned by the atmosphere, are also effected when the air is still.

I. Temperature Effects.

When the sun shines on bare rock its surface is heated and expanded, and the expanded particles crowd one another with great force. Since rock is a poor conductor of heat its surface is heated and expanded notably more than parts beneath the surface. It follows that strains are set up between the expanded outer portion and the cooler and less expanded parts within. In the cooling of the same rock mass it is the outermost portion which cools first and fastest, and, contracting as it cools, strains are again set up between the outer part, which is cooled more, and the inner part, which is cooled less. The result may be illustrated by the effect of cold water on hot glass, or of hot water on cold glass. In either case the fracture is the result of the sudden and considerable differential expansion or contraction. Since the heating and cooling of rock are much slower than the heating and cooling of glass under the conditions mentioned, the rupturing effects are less conspicuous, but none the less real. The actual effects of temperature changes are illustrated by familiar phenomena. The surface portions of bowlders exposed to the sun are frequently seen to be shelling off ([Fig. 26]). The loosened concentric shells may be a fraction of an inch, or sometimes even several inches in thickness. This process of exfoliation affects not only bowlders, but bare rock surfaces wherever exposed to the sun (Figs. [27], [28]). It is often conspicuous on the faces of cliffs.