M. Ritter of Jena, Wollaston, Beckman and others, have found that the rays of the spectrum are possessed of certain chemical properties—that beyond the least brilliant extremity, namely, a little beyond the violet ray, there are invisible rays which act chemically, while they have neither the power of heating nor illuminating bodies. Muriate of silver exposed to the action of the red rays becomes blackish; a greater effect is produced by the yellow: a still greater by the violet, and the greatest of all by the invisible rays beyond the violet. When phosphorus is exposed to the action of the invisible rays beyond the red, it emits white fumes; but the invisible rays beyond the violet extinguish them. The influence of these rays is daily seen in the change produced upon vegetable colours, which fade, when frequently exposed to the direct influence of the sum. What object they are destined to accomplish in the general economy of nature, is not yet distinctly known; we cannot however doubt that they are essentially requisite to various processes going forward in the material system. And we know that, not only the comfort of all the tribes of the living world, but the very existence of the animal and vegetable creation depends upon the unremitting agency of the Calorific rays.
It has likewise been lately discovered that certain rays of the spectrum, particularly the violet, possesses the property of communicating the magnetic power. Dr. Morichini, of Rome, appears to have been the first who found that the violet rays of the spectrum had this property. The result of his experiments, however, was involved in doubt, till it was established by a series of experiments instituted by Mrs. Somerville, whose name is so well known in the scientific world. This lady having covered half of a sewing-needle, about an inch long, with paper, she exposed the other half for two hours, to the violet rays. The needle had then acquired North polarity. The indigo rays produced nearly the same effect; and the blue and green rays produced it in a still less degree. In the yellow, orange, red and invisible rays, no magnetic influence was exhibited, even though the experiment was continued for three successive days. The same effects were produced by enclosing the needle in blue or green glass, or wrapping it in blue and green ribbands one half of the needle being always covered with paper.
One of the most curious discoveries of modern times, in reference to the solar spectrum, is that of Fraunhofer of Munich—one of the most distinguished artists and opticians on the Continent.[13] He discovered that the spectrum is covered with dark and coloured lines, parallel to one another, and perpendicular to the length of the spectrum; and he counted no less than 590 of these lines. In order to observe these lines, it is necessary to use prisms of the most perfect construction, of very pure glass, free of veins—to exclude all extraneous light, and even to stop those rays which form the coloured spaces, which we are not examining. It is necessary also to use a magnifying instrument, and the light must enter and emerge from the prism at equal angles. One of the important practical results of this discovery is, that those lines are fixed points in the spectrum, or rather, that they have always the same position in the coloured spaces in which they are found. Fraunhofer likewise discovered in the spectrum produced by the light of Venus, the same streaks, as in the solar spectrum; in the spectrum of the light of Sirius, he perceived three large streaks which, according to appearance, had no resemblance to those of the light of the sun; one of them was in the green, two in the blue. The stars appear to differ from one another in their streaks. The electric light differs very much from the light of the sun and that of a lamp, in regard to the streaks of the spectrum—‘This experiment may also be made, though in an imperfect manner, by viewing a narrow slit between two nearly closed window-shutters, through a very excellent glass prism held close to the eye, with the refracting angle parallel to the line of light. When the spectrum is formed by the sun’s rays, either direct or indirect, as from the sky, clouds, rainbow, moon, or planets, the black bands are always found to be in the same parts of the spectrum, and under all circumstances to maintain the same relative position, breadth and intensities.’
From what has been stated in reference to the solar spectrum it will evidently appear, that white light is nothing else than a compound of all the prismatic colours; and this may be still farther illustrated by shewing, that the seven primary colours, when again put together, recompose white light. This may be rudely proved for the purpose of illustration, by mixing together seven different powders, having the colours and proportion of the spectrum; but the best mode, on the whole, is the following. Let two circles be drawn on a smooth round board, covered with white paper, as in fig. 34: Let the outermost be divided into 360 equal parts; then draw seven right lines as A,B,C, &c., from the center to the outermost circle, making the lines A and B include 80 degrees of that circle. The lines B and C, 40 degrees; C and D, 60; D and E, 60; E and F, 48; F and G, 27; G and A, 45. Then between these two circles paint the space AG red, inclining to orange near G; GF orange, inclining to yellow near F; FE yellow, inclining to green near E; ED green, inclining to blue near D; DC blue, inclining to indigo near C; CB indigo, inclining to violet near B; and BA violet, inclining to a soft red near A. This done, paint all that part of the board black which lies within the inner circle; and putting an axis through the centre of the board, let it be turned swiftly round that axis, so that the rays proceeding from the above colours, may be all blended and mixed together in coming to the eye. Then the whole coloured part will appear like a white ring a little grayish—not perfectly white, because no art can prepare or lay on perfect colours, in all their delicate shades, as found in the real spectrum.
figure 34.
That all the colours of light, when blended together in their proper proportions, produce a pure white is rendered certain by the following experiment. Take a large convex glass, and place it in the room of the paper or screen on which the solar spectrum was depicted (LM fig. 31), the glass will unite all the rays which come from the prism, if a paper is placed to receive them, and you will see a circular spot of a pure lively white. The rays will cross each other in the focus of the glass, and, if the paper be removed a little further from that point, you will see the prismatic colours again displayed, but in an inverted order, owing to the crossing of the rays.
SECT. 2.—ON THE COLOURS OF NATURAL OBJECTS.
From what has been stated above we may learn the true cause of those diversified hues exhibited by natural and artificial objects, and the variegated colouring which appears on the face of nature. It is owing to the surfaces of bodies being disposed to reflect one colour rather than another. When this disposition is such that the body reflects every kind of ray, in the mixed state in which it receives them, that body appears white to us—which, properly speaking, is no colour, but rather the assemblage of all colours. If the body has a fitness to reflect one sort of rays more abundantly than others, by absorbing all the others, it will appear of the colour belonging to that species of rays. Thus, the grass is green, because it absorbs all the rays except the green. It is these green rays only which the grass, the trees, the shrubs, and all the other verdant parts of the landscape reflect to our sight, and which make them appear green. In the same manner the different flowers reflect their respective colours; the rose, the red rays; the violet, the blue; the jonquil, the yellow; the marigold, the orange, and every object, whether natural or artificial, appears of that colour which its peculiar texture is fitted to reflect. A great number of bodies are fitted to reflect at once several kinds of rays, and of consequence they appear under mixed colours. It may even happen, that of two bodies which should be green, for example, one may reflect the pure green of light, and the other the mixture of yellow and blue. This quality, which varies to infinity, occasions the different kinds of rays to unite in every possible manner, and every possible proportion; and hence the inexhaustible variety of shades and hues which nature has diffused over the landscape of the world. When a body absorbs nearly all the light which reaches it, that body appears black. It transmits to the eye so few reflected rays that it is scarcely perceptible in itself, and its presence and form make no impression upon us, unless as it interrupts the brightness of the surrounding space. Black is, therefore, the absence of all the coloured rays.
It is evident, then, that all the various assemblages of colours which we see in the objects around us, are not in the bodies themselves, but in the light which falls upon them. There is no colour inherent in the grass, the trees, the fruits, and the flowers, nor even in the most splendid and variegated dress that adorns a lady. All such objects are as destitute of colour, in themselves, as bodies which are placed in the centre of the earth, or as the chaotic materials out of which our globe was formed, before light was created. For where there is no light, there is no colour. Every object is black, or without colour, in the dark, and it only appears coloured as soon as light renders it visible. This is further evident from the following experiment. If we place a coloured body in one of the colours of the spectrum which is formed by the prism, it appears of the colour of the rays in which it is placed. Take, for example, a red rose, and expose it first to the red rays, and it will appear of a more brilliant ruddy hue. Hold it in the blue rays, and it appears no longer red, but of a dingy blue colour, and in like manner its colour will appear different, when placed in all the other differently coloured rays. This is the reason why the colours of objects are essentially altered by the nature of the light in which they are seen. The colours of ribbons and various pieces of silk or woollen stuff are not the same when viewed by candle-light as in the day time. In the light of a candle or a lamp, blue often appears green, and yellow objects assume a whitish aspect. The reason is that the light of a candle is not so pure a white as that of the sun, but has a yellowish tinge, and therefore, when refracted by the prism, the yellowish rays are found to predominate, and the superabundance of yellow rays gives to blue objects a greenish hue.