A photographic negative is taken of the original drawing and a positive made on a film of bichromate gelatine. Wherever light reaches the film, the gelatine is rendered more or less insoluble according to the intensity of the light acting upon it; through the dark parts of the negative but little light will pass, so that the gelatine will remain soluble.
The exposure of the positive having been made, the film, which may be mounted on paper, is inked with lithographic ink in the dark room and then washed. The pigment will adhere to those parts acted on by light, but will wash away from those regions unacted upon; obviously the half-tones will retain ink in direct proportion to their density.
The developed positive is then transferred to a stone or zinc plate and impressions taken as in pure lithography for the dark parts are resistant to water and will take the ink, whilst the high lights will retain water and so will not be inked. The intermediate tones will take the pigment according to their density.
In distinction to the previous methods, corrections cannot be made except in so far as the negative can be touched up.
COLLOTYPE.—Of the various photolithographic methods which have from time to time been employed, collotype is the one in most general use at the present time, especially for the reproduction of photographs.
Collotype is a simple process which does not require so extensive a technical knowledge and ability as some of those previously described. But notwithstanding this, the results are sometimes unsatisfactory and unequal; faults due to indifferent originals and to unsatisfactory conditions obtaining in the work rooms. The great drawbacks to good collotype are cold and dampness, and it is for these reasons that continental firms, blessed with a more stable climate, often produce much the best work. Provided the workshops are properly heated, the collotypers of this country ought to be able to turn out good work at all times of the year; indeed, the best firms do.
For this and for other processes in which photographs form the originals to be reproduced, authors should send the negative to the collotyper; if this be impossible, positives of the best possible quality, printed on ordinary P.O.P. paper, toned to various shades of purple, and also on smooth bromide paper, in ordinary black tones, should be provided in order that the collotyper can choose the print he most prefers to work with. Also, it is usual to glaze the prints.
The method is as follows. A piece of british plate glass, about half-an-inch in thickness, is ground on one side with fine emery powder, and then thoroughly washed and dried. The plate is covered with a filtered mixture of the colloids sodium silicate and dextrine or albumin, and placed in a warm oven to dry. If metal plates are used, such as zinc or copper, this preliminary coating is unnecessary; glass plates, however, must have the substratum in order that the sensitised gelatine—which is next put on—may stick.
When the plate is dry, it is thoroughly washed with water in order to remove any free silicate; it is then dried and put away until required for use.
The sensitising solution is made up of gelatine and bichromate of potash dissolved in water; before use it is filtered, freed from air bubbles and heated to not more than 120° F. The plate is now placed on a stand, which is provided with levelling screws, in the oven, and, when the temperature has reached 120° F., an amount of the bichromate gelatine solution sufficient to make a thickness of film proper for the mode of printing to be employed is poured upon the plate.