Carbonate of soda he calls sagimen vitri, and salt of soda. He mentions plants which yield it when burnt, points out the method of purifying it, and even describes the method of rendering it caustic by means of quicklime.[120]
3. Saltpetre, or nitrate of potash, was known to him; and Geber is the first writer in whom we find an account of this salt. Nothing is said respecting its origin; but there can be little doubt that it came from India, where it was collected, and known long before Europeans were acquainted with it. The knowledge of this salt was probably one great cause of the superiority of the Arabians over Europeans in chemical knowledge; for it enabled them to procure nitric acid, by means of which they dissolved all the metals known in their time, and thus acquired a knowledge of various important saline compounds, which were of considerable importance.
There is a process for preparing saltpetre artificially, in several of the Latin copies of Geber, though it does not appear in our English translation. The method was to dissolve sagimen vitri, or carbonate of soda, in aqua fortis, to filter and crystallize by evaporation.[121] If this process be genuine, it is obvious that Geber must have been acquainted with nitrate of soda; but I have some doubts about the genuineness of the passage, because the term aqua fortis occurs in it. Now this term occurs nowhere else in Geber’s work: even when he gives the process for procuring nitric acid, he calls it simply water; but observes, that it is a water possessed of much virtue, and that it constitutes a precious instrument in the hands of the man who possesses sagacity to use it aright.
4. Sal ammoniac was known to Geber, and seems to have been quite common in his time. There is no evidence that it was known to the Greeks or Romans, as neither Dioscorides nor Pliny make any allusion to it. The word in old books is sometimes sal armoniac, sometimes sal ammoniac. It is supposed to have been brought originally from the neighbourhood of the temple of Jupiter Ammon: but had this been the case, and had it occurred native, it could scarcely have been unknown to the Romans, under whose dominions that part of Africa fell. In the writings of the alchymists, sal ammoniac is mentioned under the following whimsical names: Anima sensibilis,
Aqua duorum fratrum ex sorore,
Aquila,
Lapis aquilinis,
Cancer,
Lapis angeli conjungentis,
Sal lapidum,
Sal alocoph.
Geber not only knew sal ammoniac, but he was aware of its volatility; and gives various processes for subliming it, and uses it frequently to promote the sublimation of other bodies, as of oxides of iron and copper. He gives also a method of procuring it from urine, a liquid which, when allowed to run into putrefaction, is known to yield it in abundance. Sal ammoniac was much used by Geber, in his various processes to bring the inferior metals to a state of greater perfection. By adding it or common salt to aqua fortis, he was enabled to dissolve gold, which certainly could not be accomplished in the time of Dioscorides or Pliny. The description, indeed, of Geber’s process for dissolving gold is left on purpose in a defective state; but an attentive reader will find no great difficulty in supplying the defects, and thus understanding the whole of the process.
5. Alum, precisely the same as the alum of the moderns, was familiarly known to Geber, and employed by him in his processes. The manufacture of this salt, therefore, had been discovered between the time when Pliny composed his Natural History and the eighth century, when Geber wrote; unless we admit that the mode of making it had been known to the Tyrian dyers, but that they had kept the secret so well, that no suspicion of its existence was entertained by the Greeks and Romans. That they employed alumina as a mordant in some of their dyes, is evident; but there is no proof whatever that alum, in the modern sense of the word, was known to them.
Geber mentions three alums which he was in the habit of using; namely, icy alum, or Rocca alum; Jamenous alum, or alum of Jameni, and feather alum. Rocca, or Edessa, in Syria, is admitted to have been the place where the first manufactory of alum was established; but at what time, or by whom, is quite unknown: we know only that it must have been posterior to the commencement of the Christian era, and prior to the eighth century, when Geber wrote. Jameni must have been another locality where, at the time of Geber, a manufactory of alum existed. Feather alum was undoubtedly one of the native impure varieties of alum, known to the Greeks and Romans. Geber was in the habit of distilling alum by a strong heat, and of preserving the water which came over as a valuable menstruum. If alum be exposed to a red heat in glass vessels, it will give out a portion of sulphuric acid: hence water distilled from alum by Geber was probably a weak solution of sulphuric acid, which would undoubtedly act powerfully as a solvent of iron, and of the alkaline carbonates. It was probably in this way that he used it.
6. Sulphate of iron or copperas, as it is called (cuperosa), in the state of a crystalline salt, was well known to Geber, and appears in his time to have been manufactured.
7. Baurach, or borax, is mentioned by him, but without any description by which we can know whether or not it was our borax: the probability is that it was. Both glass and borax were used by him when the oxides of metals were reduced by him to the metallic state.
8. Vinegar was purified by him by distilling it over, and it was used as a solvent in many of his processes.