His paper on the prodigious bank of fossil shells at Touraine, from which the inhabitants draw manure in such quantities for their fields, deserves attention in a geological point of view. But his paper on flints and stones is not so valuable; it consists in speculations, which, from the infant state of chemical analysis when he wrote, could not be expected to lead to correct conclusions.
I pass over many of the papers of this most indefatigable man, because they are not connected with chemistry; but his history of insects constitutes a charming book, and contains a prodigious number of facts of the most curious and important nature. This book alone, supposing Reaumur had done nothing else, would have been sufficient to have immortalized the author.
In the year 1722 he published his work on the art of converting iron into steel, and of softening cast-iron. At that time no steel whatever was made in France; the nation was supplied with that indispensable article from foreign countries, chiefly from Germany. The object of Reaumur’s book was to teach his countrymen the art of making steel, and, if possible, to explain the nature of the process by which iron is changed into steel. Reaumur concluded from his experiments, that steel is iron impregnated with sulphureous and saline matters. The word sulphureous, as at that time used, was nearly synonymous with our present term combustible. The process which he found to answer, and which he recommends to be followed, was to mix together 4 parts of soot 2 parts of charcoal-powder 2 parts of wood-ashes 1½ parts of common salt.
The iron bars to be converted into steel were surrounded with this mixture, and kept red-hot till converted into steel. Reaumur’s notion of the difference between iron and steel was an approximation to the truth. The saline matters which he added do not enter into the composition of steel; and if they did, so far from improving, they would injure its qualities. But the charcoal and soot, which consist chiefly of carbon, really produce the desired effect; for steel is a combination of iron and carbon.
In consequence of these experiments of Reaumur, it came to be an opinion entertained by chemists, that steel differed from iron merely by containing a greater proportion of phlogiston; for the charcoal and soot with which the iron bars were surrounded was considered as consisting almost entirely of phlogiston; and the only useful purpose which they could serve, was supposed to be to furnish phlogiston. This opinion continued prevalent till it was overturned towards the end of the last century, first by the experiments of Bergmann, and afterwards by those of Berthollet, Vandermond, and Monge, published in the Memoirs of the French Academy for 1786 (page 132). In this elaborate memoir the authors take a view of all the different processes followed in bringing iron from the ore to the state of steel: they then give an account of the researches of Reaumur and of Bergmann; and lastly relate their own experiments, from which they finally draw, as a conclusion, that steel is a compound of iron and carbon.
The regent Orleans, who at that time administered the affairs of France, thought that this work of Reaumur was deserving a reward, and accordingly offered him a pension of 12,000 livres. Reaumur requested of the regent that this pension should be given in the name of the academy, and that after his death it should continue, and be devoted to defray the necessary expenses towards bringing the arts into a state of perfection. The request was granted, and the letters patent made out on the 22d of December, 1722.
At that time tin-plate, as well as steel, was not made in France; but all the tin-plates wanted were brought from Germany, where the processes followed were kept profoundly secret. Reaumur undertook to discover a method of tinning iron sufficiently cheap to admit the article to be manufactured in France—and he succeeded. The difficulty consisted in removing the scales with which the iron plates, as prepared, were always covered. These scales consist of a vitrified oxide of iron, to which the tin will not unite. Reaumur found, that when these plates are steeped in water acidulated by means of bran, and then allowed to rust in stoves, the scales become loose, and are easily detached by rubbing the plates with sand. If after being thus cleansed they are plunged into melted tin, covered with a little tallow to prevent oxidizement, they are easily tinned. In consequence of this explanation of the process by Reaumur, tin-plate manufactories were speedily established in different parts of France. It was about the same time, or only a little before it, that tin-plate manufactories were first started in England. The English tin-plate was much more beautiful than the German, and therefore immediately preferred to it; because in Germany the iron was converted into plates by hammering, whereas in England it was rolled out. This made it much smoother, and consequently more beautiful.
Another art, at that time unknown in France, and indeed in every part of Europe except Saxony, was the art of making porcelain, a name given to the beautiful translucent stoneware which is brought from China and Japan. Reaumur undertook to discover the process employed in making it. He procured specimens of porcelain from China and Japan, and also of the imitations of those vessels at that time made in various parts of France and other European countries. The true porcelain remained unaltered, though exposed to the most violent heat which he was capable of producing; but the imitations, in a furnace heated by no means violently, melted into a perfect glass. Hence he concluded, that the imitation-porcelains were merely glass, not heated sufficiently to be brought into fusion; but true porcelain he conceived to be composed of two different ingredients, one of which is capable of resisting the most violent heat which can be raised, but the other, when heated sufficiently, melts into a glass. It is this last ingredient that gives porcelain its translucency, while the other makes it refractory in the fire. This opinion of Reaumur was soon after confirmed by Father d’Entrecolles, a French missionary in China, who sent some time after a memoir to the academy, describing the mode followed by the Chinese in the manufactory of their porcelain. Two substances are employed by them, the one called kaolin and the other petunse. It is now known that kaolin is what we call porcelain-clay, and that petunse is a fine white felspar. Felspar is fusible in a violent heat, but porcelain-clay is refractory in the highest temperatures that we have it in our power to produce in furnaces.
Reaumur made another curious observation on glass, which has been, since his time, employed very successfully to explain the appearances of many of our trap-rocks. If a glass vessel, properly secured in sand, be raised to a red heat, and then allowed to cool very slowly, it puts off the appearance of glass and assumes that of stoneware, or porcelain. Vessels thus altered have received the name of Reaumur’s porcelain. They are much more refractory than glass, and therefore may be exposed to a pretty strong red heat without any danger of softening or losing their shape. This change is occasioned by the glass being kept long in a soft state: the various substances of which it is composed are at liberty to exercise their affinities and to crystallize. This makes the vessel lose its glassy structure altogether. In like manner it was found by Sir James Hall and Mr. Gregory Watt, that when common greenstone was heated sufficiently, and then rapidly cooled, it melted and concreted into a glass; but if after having been melted it was allowed to cool exceedingly slowly, the constituents again crystallized and arranged themselves as at first—so that a true greenstone was again formed. In the same way lavas from a volcano either assume the appearance of slag or of stone, according as they have cooled rapidly or slowly. Many of the lavas from Vesuvius cannot be distinguished from our greenstones.
Reaumur’s labours upon the thermometer must not be omitted here; because he gave his name to a thermometer, which was long used in France and in other parts of Europe. The first person that brought thermometers into a state capable of being compared with each other was Sir Isaac Newton, in a paper published in the Philosophical Transactions for 1701. Fahrenheit, of Amsterdam, was the first person that put Newton’s method in practice, by fixing two points on his scale, the freezing-water point and the boiling-water point, and dividing the interval between them into one hundred and eighty degrees.