The first of these opinions occasioned a controversy between Mr. Cavendish, and Mr. Kirwan, who maintained that carbonic acid is always produced when air is phlogisticated. Two papers on this subject by Kirwan, and one by Cavendish, are inserted in the Philosophical Transactions for 1784, each remarkable examples of the peculiar manner of the respective writers. All the arguments of Kirwan are founded on the experiments of others. He displays great reading, and a strong memory; but does not discriminate between the merits of the chemists on whose authority he founds his opinions. Mr. Cavendish, on the other hand, never advances a single opinion, which he has not put to the test of experiment; and never suffers himself to go any further than his experiment will warrant. Whatever is not accurately determined by unexceptionable trials, is merely stated as a conjecture on which little stress is laid.

In the first of these celebrated papers, Mr. Cavendish has drawn a comparison between the phlogistic and antiphlogistic theories of chemistry; he has shown that each of them is capable of explaining the phenomena in a satisfactory manner; though it is impossible to demonstrate the truth of either; and he has given the reasons which induced him to prefer the phlogistic theory—reasons which the French chemists were unable to refute, and which they were wise enough not to notice. There cannot be a more striking proof of the influence of fashion, even in science, and of the unwarrantable precipitation with which opinions are rejected or embraced by philosophers, than the total inattention paid by the chemical world to this admirable dissertation. Had Mr. Kirwan adopted the opinions of Mr. Cavendish, when he undertook the defence of phlogiston, instead of trusting to the vague experiments of inaccurate chemists, he would not have been obliged to yield to his French antagonists, and the antiphlogistic theory would not so speedily have gained ground.

Such is an epitome of the chemical papers of Mr. Cavendish. They contain five notable discoveries; namely, 1. The nature and properties of hydrogen gas. 2. The solubility of bicarbonates of lime and magnesia in water. 3. The exact proportion of the constituents of common air. 4. The composition of water. 5. The composition of nitric acid. It is to him also that we are indebted for our knowledge of the freezing point of mercury; and he was likewise the first person who showed that potash has a stronger affinity for acids than soda has. His experiments on the subject are to be found in a paper on Mineral Waters, published in the Philosophical Transactions, by Dr. Donald Monro.

END OF VOL. I.

C. WHITING, BEAUFORT HOUSE, STRAND.


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