Now, undoubtedly these two arrangements would produce a great change in the nature of the compound.
There is something in the vegetable acids quite different from the acids of the inorganic kingdom, and which would lead to the suspicion that the electro-chemical theory will not apply to them as it does to the others. In the acids of carbon, sulphur, phosphorus, selenium, &c., we find one atom of a positive substance united to one, two, or three of a negative substance: we are not surprised, therefore, to find the acid formed negative also. But in acetic and succinic acids we find every atom of oxygen united with two electro-positive atoms: the wonder then is, that the acid should not only retain its electro-negative properties, but that it should possess considerable power as an acid. In benzoic acid, for every atom of oxygen, there are present no fewer than seven electro-positive atoms.
Berzelius has returned to these analytical experiments repeatedly, so that at last he has brought his results very near the truth indeed. It is to his labours chiefly that the great progress which the atomic theory has made is owing.
In the year 1814 there appeared in the Philosophical Transactions a description of a Synoptical Scale of Chemical Equivalents, by Dr. Wollaston. In this paper we have the equivalents or atomic weights of seventy-three different bodies, deduced chiefly from a sagacious comparison of the previous analytical experiments of others, and almost all of them very near the truth. These numbers are laid down upon a sliding rule, by means of a table of logarithms, and over against them the names of the substances. By means of this rule a great many important questions respecting the substances contained on the scale may be solved. Hence the scale is of great advantage to the practical chemist. It gives, by bare inspection, the constituents of all the salts contained on it, the quantity of any other ingredient necessary to decompose any salt, and the weights of the new constituents that will be formed. The contrivance of this scale, therefore, may be considered as an important addition to the atomic theory. It rendered that theory every where familiar to all those who employed it. To it chiefly we owe, I believe, the currency of that theory in Great Britain; and the prevalence of the mode which Dr. Wollaston introduced, namely, of representing the atom of oxygen by unity, or at least by ten, which comes nearly to the same thing.
Perhaps the reader will excuse me if to the preceding historical details I add a few words to make him acquainted with my own attempts to render the atomic theory more accurate by new and careful analyses. I shall not say any thing respecting the experiments which I undertook to determine the specific gravity of the gases; though they were performed with much care, and at a considerable expense, and though I believe the results obtained approached accuracy as nearly as the present state of chemical apparatus enables us to go. In the year 1819 I began a set of experiments to determine the exact composition of the salts containing the different elementary bodies by means of double decomposition, as was done by Wenzel, conceiving that in that way the results would be very near the truth, while the experiments would be more easily made. My mode was to dissolve, for example, a certain weight of muriate of barytes in distilled water, and then to ascertain by repeated trials what weight of sulphate of soda must be added to precipitate the whole of the barytes without leaving any surplus of sulphuric acid in the liquid. To determine this I put into a watch-glass a few drops of the filtered liquor consisting of the mixture of solutions of the two salts: to this I added a drop of solution of sulphate of soda. If the liquid remained clear it was a proof that it contained no sensible quantity of barytes. To another portion of the liquid, also in a watch-glass, I added a drop of muriate of barytes. If there was no precipitate it was a proof that the liquid contained no sensible quantity of sulphuric acid. If there was a precipitate, on the addition of either of these solutions, it showed that there was an excess of one or other of the salts. I then mixed the two salts in another proportion, and proceeded in this way till I had found two quantities which when mixed exhibited no evidence of the residual liquid containing any sulphuric acid or barytes. I considered these two weights of the salts as the equivalent weights of the salt, or as weights proportional to an integrant particle of each salt. I made no attempt to collect the two new formed salts and to weigh them separately.
I published the result of my numerous experiments in 1825, in a work entitled "An Attempt to establish the First Principles of Chemistry by Experiment." The most valuable part of this book is the account of the salts; about three hundred of which I subjected to actual analysis. Of these the worst executed are the phosphates; for with respect to them I was sometimes misled by my method of double decomposition. I was not aware at first, that, in certain cases, the proportion of acid in these salts varies, and the phosphate of soda which I employed gave me a wrong number for the atomic weight of phosphoric acid.
CHAPTER VII.
OF THE PRESENT STATE OF CHEMISTRY.