If the tar be gently heated in a closed vessel it will evaporate and the vapour can be led to another vessel, there cooled and converted back into a liquid. This
looks rather like doing work for nothing, but the various liquids, of which tar is a mixture, evaporate at different temperatures, so that this furnishes a means of separating them. The first liquid thus procured is known as coal tar naphtha, and if it be again distilled it can be subdivided further, the first liquid separated from it being known as Benzine. This, again, is another of those almost numberless things which consist of carbon and hydrogen. Also, like the other similar substances which we have been discussing, it can, if treated with nitric acid, be made to take into partnership a quantity of oxygen and nitrogen.
Thus we get nitro-benzene. We can repeat the process, when it will take more and become di-nitro-benzene. Again we can repeat it, thus producing tri-nitro-benzene.
The second liquid separated from coal tar naphtha is called Toluene, which again is composed of carbon and hydrogen in slightly different proportions. Like its confrère benzene it, too, can be treated with nitric acid, becoming nitro-toluene and then di-nitro-toluene and finally tri-nitro-toluene, the deadly explosive of which we read in the papers as T.N.T.
After the naphtha has been removed from the tar another substance is obtained called Phenol, which in a prepared form is familiar to us all as the disinfectant Carbolic Acid. It also can be treated with nitric acid, to produce tri-nitro-phenol, otherwise known as Picric Acid, which after a little further treatment becomes the famous "Lyddite."
Most of the actual explosives used in warfare are
prepared from one or more of the above-mentioned compounds. For example, nitro-glycerine and gun-cotton, having been dissolved in acetone (another compound of carbon, hydrogen and oxygen) and a little vaseline added, form a soft gelatinous substance which on being squeezed through a fine hole comes out looking like a cord or string, and hence is called Cordite.
Other explosives are finished in the form of sheets, the dissolved gun-cotton or whatever it may be being rolled between hot rollers which give it the convenient form of sheets and at the same time evaporate the solvent.
By combining these various substances various characteristics can be given to the finished explosive. For instance, the one which drives the shell from the gun, known as the propellant, must not be too sudden in its action. It must push steadily. Its purpose is to drive the shell not to burst the gun, wherefore its action must be comparatively slow and continuous so long as the shell is still in the gun. It must "follow through" as the golf player would put it.
The charge in the shell, however, needs to go off with the greatest possible violence so as to blow the shell to pieces and to scatter the fragments so that they do the maximum of damage.