Refined grades, melting above 79° C., are marketed as white, crystalline lumps or flakes. Their principal uses are in the manufacture of intermediates, dyes, medicinals, solvents, and textile assistants; as moth repellants; as a lubricant when mixed with rapeseed oil; to remove the “bloom” from lubricating oils; as a preservative for rubber goods and animal skins; and in explosives (trinitro naphthalene). In 1936 more than 75 coal-tar intermediates made from naphthalene were commercially produced in the United States. Of the 75 million pounds of these intermediates produced in that year, 31 million pounds were phthalic anhydride, an important component of synthetic resins of the alkyd type.
United States production.
Crude naphthalene is produced in the United States by byproduct coke-oven operators, gas works that produce their own coal tar, and also by firms that purchase coal tar and distill it. Statistics of production by groups are shown in table [33].
Table 33.—Crude naphthalene: United States production, 1918-37
| Year | By producers of tar | By purchasers of tar | Total production | ||||||
|---|---|---|---|---|---|---|---|---|---|
| Quantity | Value | Unit value | Quantity | Value | Unit value | Quantity | Value | Unit value | |
| 1,000 pounds | Per pound | 1,000 pounds | Per pound | 1,000 pounds | Per pound | ||||
| 1918 | 40,138 | $1,281,440 | $0.032 | 40,138 | $1,281,440 | $0.032 | |||
| 1919 | 12,612 | 327,201 | .030 | 12,612 | 327,201 | .026 | |||
| 1923 | 11,872 | $201,824 | $0,017 | 41,453 | 652,148 | .016 | 53,325 | 853,972 | .016 |
| 1925 | 9,239 | 92,389 | .010 | 34,135 | 519,773 | .015 | 43,374 | 612,162 | .014 |
| 1926 | 7,747 | 100,709 | .013 | 45,166 | 494,986 | .011 | 52,913 | 595,695 | .011 |
| 1927 | 8,303 | 91,331 | .011 | 45,298 | 470,806 | .010 | 53,601 | 562,137 | .010 |
| 1928 | 112,182 | 146,186 | .012 | 35,180 | 395,059 | .011 | 47,362 | 541,245 | .011 |
| 1929 | 119,761 | 316,182 | .016 | 19,502 | 366,491 | .020 | 39,263 | 682,673 | .017 |
| 1930 | 112,640 | 151,681 | .012 | 18,617 | 304,574 | .020 | 31,257 | 456,255 | .015 |
| 1931 | 17,623 | 76,229 | .010 | 13,311 | 199,665 | .015 | 20,934 | 275,894 | .013 |
| 1932 | 14,632 | 41,690 | .09 | 8,961 | 125,453 | .014 | 13,593 | 167,143 | .012 |
| 1933 | 16,618 | 66,181 | .010 | 24,003 | 360,040 | .015 | 30,621 | 426,221 | .014 |
| 1934 | 110,743 | 139,665 | .013 | 27,179 | 489,222 | .018 | 37,922 | 628,887 | .016 |
| 1935 | 112,937 | 168,185 | .013 | 34,716 | 624,890 | .018 | 47,653 | 793,075 | .017 |
| 1936 | 137,552 | 600,836 | .016 | 51,984 | 1,195,632 | .023 | 89,536 | 1,796,468 | .020 |
| 1937 | 160,797 | 1,215,942 | .020 | 55,182 | 1,545,100 | .028 | 115,979 | 2,667,522 | .023 |
1 Crude and refined. Refined naphthalene included here is probably small so that the figures here and those for total production are substantially accurate.
Source: Bureau of Mines and U.S. Tariff Commission.
Refined naphthalene is obtained from domestic crude, imported crude, and recently from petroleum cracking and hydrogenation. Table [34] shows the annual production and sales of refined naphthalene since 1916. The difference between the figures for the quantity produced and that sold represents the amount used by refiners in the manufacture of other products.
Table 34.—Refined naphthalene: United States production and sales, 1917-37