ĊaS⃛, calcium sulphate; F̋e, iron disulphide
This form of notation was quite extensively employed for a time, especially by mineralogists, but it was entirely abandoned later.
It is interesting to notice that Dalton, who lived until 1844, to reach the age of 78, differed from other chemists in refusing to accept the letter-symbols of Berzelius. In a letter written to Graham in 1837 he said: “Berzelius’s symbols are horrifying. A young student in chemistry might as soon learn Hebrew as to make himself acquainted with them. They appear like a chaos of atoms ... and to equally perplex the adepts of science, to discourage the learner, as well as to cloud the beauty and simplicity of the atomic theory.”
This forcibly expressed opinion was apparently tinged with self-esteem, but there is no doubt that Dalton was sincere in believing that the atoms were best represented by his circular symbols, because, as is well known, he thought that all the atoms were spherical in form, and it is evident that circles give the proper picture of spherical objects. At the present time some insight as to the structure of atoms is being gained, and it appears possible that the time may come when pictures of their external appearance that are not wholly imaginary may be made.
Changes in Formulas.—Even before the year 1826, Berzelius displayed great skill in arriving at many formulas that agree with our present ones, for example, H2O for water, ZnCl2 for zinc chloride, N2O5 for nitric acid (anhydride), CaO for calcium oxide, CO and CO2 for the oxides of carbon, and many others. But at the same period other authorities, especially Gay-Lussac in France and Gmelin in Germany, on account of a lack of appreciation for Avogadro’s principle and for other reasons, such as the use of symbols to represent combining weights rather than atoms, were using different formulas for some of these compounds, such as HO, ZnCl and NO5, so that their formulas for many of the compounds of hydrogen, chlorine, nitrogen and several other elements differed from those of Berzelius. The employment of different formulas involved the use of different atomic or combining weights. For example, with the formula H2O for water the composition by weight requires the ratio 1 to 16 for the weights of the hydrogen and oxygen atoms, while with HO the ratio is 1 to 8.
Berzelius attempted to bring about greater uniformity in formulas and atomic weights by making changes in his table of atomic weights published in 1826. He practically doubled the relative atomic weights of hydrogen, chlorine, nitrogen, and of the other elements that gave twice as many atoms in his formulas as in those of others, and at the same time he wrote the symbols of these elements with a bar across them to indicate that they represented double atoms. For example, he wrote:
H̶O ZnC̶l N̶O5,
instead of
H2O, ZnCl2 N2O5
This appears to have been an unfortunate concession to the views of others on the part of Berzelius, for the barred symbols were not generally adopted, partly on account of difficulties in printing, and the great achievement in theory made by him was lost sight of for a long period of time.