“Dr. S. P. Thompson has given the following interesting details in regard to this subject: In looking over an old volume of the Journal de Paris, I found, under date of the Twenty-second Ventose, An. X (March 12, 1802), this passage, which evidently refers to an exhibition of the electric arc: ‘Citizen (E. G.) Robertson, the inventor of the phantasmagoria (magic lantern), is at present performing some interesting experiments that must doubtless advance our knowledge concerning galvanism. He has just mounted metallic piles to the number of 2500 zinc plates and as many of rosette copper. We shall forthwith speak of his results, as well as of a new experiment that he performed yesterday with two glowing carbons. The first having been placed at the base of a column of 120 zinc and silver elements, and the second communicating with the apex of the pile, they gave at the moment they were united a brilliant spark of an extreme whiteness that was seen by the entire society. Citizen Robertson will repeat the experiment on the 25th.’”
The date generally given for this discovery by Humphry Davy is 1809, but earlier accounts of his experiments are found in Cuthbertson’s “Electricity” (1807), and in several other works.
In the Phil. Mag., Vol. IX. p. 219, under date of Feb. 1, 1801, in a memoir by Dr. H. Moyes, of Edinburgh, relative to experiments made with the pile, we find the following passage: “When the column in question had reached the height of its power, its sparks were seen by daylight, even when they were made to jump with a piece of carbon held in the hand.” In the same volume of the Phil. Mag., and immediately following Dr. Moyes’ letter to Dr. Garthshore, on experiments with the voltaic pile, will be found an account of similar investigations made in Germany, and communicated by Dr. Frulander, of Berlin.
In the “Journal of the Royal Institution” (1802), Vol. I. p. 106, Davy describes a few experiments made with the pile, and says: “When instead of metals, pieces of well-calcined carbon were employed, the spark was still larger and of a clear white.” On p. 214 he describes and figures an apparatus for taking the galvano-electric spark into fluid and aeriform substances. This apparatus consisted of a glass tube open at the top, and having at the side another tube through which passed a wire that terminated in a carbon. Another wire, likewise terminating in carbon, traversed the bottom, and was cemented in a vertical position.
But all these observations are subsequent to a letter printed in “Nicholson’s Journal” for October 1800, p. 150, entitled “Additional experiments on Galvanic Electricity in a letter to Mr. Nicholson.” The letter is dated Dowry Square, Hotwells, Sept. 22, 1800, and is signed by Humphry Davy, who at this epoch was assistant to Dr. Beddoes at the Philosophical (Pneumatic) Institution of Bristol. It begins thus:
“Sir: The first experimenters in animal electricity remarked the property that well calcined carbon has of conducting ordinary galvanic action. I have found that this substance possesses the same properties as metallic bodies for the production of the spark when it is used for establishing a communication between the extremities of Signor Volta’s pile.”
Among the papers read by Davy before the Royal Society between June 30, 1808, and Feb. 13, 1814, are the following: “Electro-chemical researches on the decomposition of the earths, with observations on the metals obtained from the alkaline earths, and on the amalgam procured from ammonia”; “An account of some new analytical researches on the nature of certain bodies,” etc., and the Bakerian lecture “On some new electro-chemical researches, on various objects, particularly the metallic bodies from the alkalies and earths, and on some combinations of hydrogen”; “Elements of chemical philosophy, detailing experiments on electricity in vegetation.”
In alluding to the important subjects covered by him during the above-named period, his brother and biographer, John Davy, M.D., F.R.S., says: “I shall not attempt an analysis of these papers; I shall give merely a sketch of the most important facts and discoveries which they contain, referring the chemical reader to the original for full satisfaction. After the extraction of metallic bases from the fixed alkalies, analogies of the strongest kind indicated that the alkaline earths are similarly constituted; and he succeeded in proving this in a satisfactory manner. But, owing to various circumstances of peculiar properties, he was not able on his first attempts to obtain the metals of those earths in a tolerably pure and insulated state for the purpose of examination. On his return to the laboratory after his illness, this was one of the first undertakings. He accomplished it to a certain extent by uniting a process of Messrs. Berzelius and Pontin, who were then engaged in the same enquiry, with one of his own. By negatively electrifying the earths, slightly moistened, and mixed with red oxide of mercury, in contact with a globule of mercury, he obtained amalgams of their metallic bases; and, by distillation, with peculiar precautions, he expelled the greater part of the mercury. Even now, in consequence of the very minute quantities of the bases which he procured, and their very powerful attraction for oxygen, he was only able to ascertain a few of their properties in a hasty manner. They were of silvery lustre, solid at ordinary temperatures, fixed at a red heat, and heavier than water. At a high temperature they abstracted oxygen from the glass, and, at ordinary temperatures, from the atmosphere and water, the latter of which in consequence they decomposed. The names he proposed for them, and by which they have since been called, were barium, strontium, calcium and magnium, which latter he afterwards altered to magnesium....”
The reviewer of Davy, in the columns of the “Chemical News,” writing in 1879, states that his papers on numerous subjects flowed into the Royal Society’s archives in an uninterrupted stream, and it may be said, without exaggeration, that his work, especially during the six years from 1806 to 1812, did more for chemistry than the 60 which followed them.
Between the last-named dates, Davy was asked by the Dublin Society to give a course of lectures on electro-chemical science, which he delivered Nov. 8–29, 1810. Trinity College afterward conferred on him the degree of LL.D., and he was knighted by the Prince Regent one day before resigning from the Royal Institution, wherein he gave his farewell address on April 9, 1812.