But how to draw them from the wire?
He took a lesson from the heart
’Tis when we meet—’tis when we part,
Breaks forth the electric fire.”
Herbert Mayo, in Blackwood.
In Prof. Alfred M. Mayer’s address, delivered before the American Association at Boston, August 26, 1880, we read: “It is not generally known or appreciated that Henry and Faraday independently discovered the means of producing the electric current and the electric spark from a magnet. Tyndall, in speaking of this great discovery of Faraday, says: ‘I cannot help thinking while I dwell upon them, that this discovery of magneto-electricity is the greatest experimental result ever obtained by an investigator. It is the Mont Blanc of Faraday’s own achievements. He always worked at great elevations, but higher than this he never subsequently attained.’ And it is this same physicist who further remarks (‘Johnson’s Cycl.,’ Vol. II. pp. 26–27) that all our induction coils, our medical machines, and the electric light so far as it has been applied to lighthouses, are the direct progeny of Faraday’s discovery. In the paper here referred to (Nov. 24, 1831) he for the first time calls the ‘magnetic curves,’ formed when iron-filings are strewn around a magnet, ‘lines of magnetic force.’ All his subsequent researches upon magnetism were made with reference to those lines. They enabled him to play like a magician with the magnetic force, guiding him securely through mazes of phenomena which would have been perfectly bewildering without their aid. The spark of the extra current, which I believe was noticed for the first time by Prof. Joseph Henry, had been noticed independently by Mr. William Jenkin. Faraday at once brought this observation under the yoke of his discovery, proving that the augmented spark was the product of a secondary current evoked by the reaction of the primary upon its own wire.” The phenomenon of the spark from the extra current here alluded to was first announced by Henry in July 1832. He had observed that when the poles of a battery are united by means of a short wire of low resistance, no spark or at least a very faint one is produced, but when the poles of the battery are connected by a long copper wire and mercury cups, a brilliant spark is obtained at the moment the circuit is broken by raising one end of the wire out of its cup of mercury and also that the longer the wire and the greater the number of its helical convolutions, the more powerful would be the effect (Silliman, “Am. Jour. of Sc.,” Vol. XXII). The results of Faraday’s investigation of the extra current first appeared in the Phil. Mag. for November 1834.
The references already named give an account of many other important results attained by Faraday during 1831 and up to the date of the publication of the third series of his “Experimental Researches” (p. 76), wherein he recognizes the “Identity of Electricities derived from different sources”[60] (Vol. I. par. 265 and 360), after investigating the electricities of the machine, the pile, and of the electrical fishes, and after employing as conductors the entire plant of the metallic gas pipes and water pipes of the city of London (Phil. Trans. for 1833, p. 23; Poggendorff, Annalen, Vol. XXIX, 1833, pp. 274, 365).
In the fourth series, relating to “A New law of electric conduction” (Vol. I. par. 380, 381, 394, 410), he demonstrates the influence of what is called “the state of aggregation” upon the transmission of the current. He found that although the latter was conveyed through water it did not pass through ice. This he subsequently explained by saying that the liquid condition enables the molecule of water to turn round so as to place itself in the proper line of polarization, which the rigidity of ice prevents. This polar arrangement must precede decomposition, and decomposition is an accompaniment of conduction (Phil. Trans. for 1833, p. 507; Poggendorff, Annalen, Vol. XXXI, 1834, p. 225; also Phil. Mag., Vol. X. p. 98; “Royal Inst. Proc.,” Vol. II. p. 123; Silliman’s Journal, Vol. XXI. p. 368).
Other series (pars. 309, 450, 453–454, 472, 477, 661–662, 669, etc.) treat of “Electro-chemical or electrolytic decomposition.” The experiments of Wollaston in this line have been given under the A.D. 1801 date, where Prof. Faraday’s opinion of them is also expressed. Faraday was successful in the employment of Wollaston’s apparatus for the decomposition of water, and he afterwards devised an arrangement enabling him to effect true electro-chemical decompositions by common electricity as well as by the voltaic pile. For this, it is said, he used an electric battery consisting of fifteen jars and a plate machine having two sets of rubbers and a glass disc fifty inches in diameter, the whole presenting a surface of 1422 inches. One revolution of the plate could be made to give ten or twelve sparks, each one inch long, while the conductors afforded sparks ten to fourteen inches in length. He also devised a discharging train, to instantaneously carry off electricity of the feeblest tension by connecting a thick wire as he had previously done with the London gas and water pipes. A good description of the methods by which he succeeded with the latter apparatus in establishing the analogy between ordinary and voltaic electricity is given in the eighth “Britannica,” Vol. VIII. pp. 596–597. He had shown, at paragraph 371 and p. 105 of his “Researches,” that as a measure of quantity, a voltaic group of two small wires of platinum and zinc, placed near each other, and immersed in dilute acid for three seconds, yields as much electricity as the electrical battery, charged by thirty turns of a large machine; a fact that was established both by its momentary electro-magnetic effect, and by the amount of its chemical action, but, in order to enable him to establish a principle of definite measurement, he devised a voltameter or volta-electrometer as mentioned at paragraph No. 739 (Noad, “Manual,” p. 365). By means of this apparatus he calculated that a single grain of water in a voltaic cell will require for its decomposition a quantity of electricity equal to that liberated in 800,000 discharges of the great Leyden battery of the Royal Institution (“Researches,” par. 861). Also, that the decomposition of a single grain of water by four grains of zinc in the active cell of the voltaic circle, produces as great an amount of polarization and decomposition in the cell of decomposition, as 950,000 charges of a large Leyden battery, of several square feet of coated surface; an enormous quantity of power, equal to a most destructive thunderstorm. Tyndall remarks (“Notes on Electricity,” No. 118, also “Faraday as a Discoverer,” 1868, p. 44) that Weber and Kohlrausch ascertained that the quantity of electricity associated with one milligramme of hydrogen in water, if diffused over a cloud 1000 metres above the earth, would exert, upon an equal quantity of the opposite electricity at the earth’s surface, an attractive force of 2,268,000 kilogrammes.[61]
Faraday introduced new terms to express more specifically the circumstances attending electro-chemical decomposition. Objections had long been made to the designation poles—one positive, the other negative—on the ground that such did not convey a correct idea of the effects produced. These designations had been given under erroneous supposition that the poles exerted an attractive and repulsive energy towards the elements of the decomposing liquid, much as the poles of the magnet act towards iron. When connecting the extremities of a battery, the electricity simply makes a circuit; the current passes through the substance to be decomposed and the elements remain in operation until the connection is broken. Since the poles merely act as a path to the current he calls them electrodes (electron, electricity, odos, a way); that part of the surface of the decomposing matter which the current enters—immediately touching the positive pole—he designates as anode (ana, upward) and the part of the matter which the current leaves—next to the negative pole—cathode (kata, downward). He names electrolyte (luo, to set free) the fluid decomposed directly by electricity passing through it; the term electrolyzed meaning electro-chemically decomposed. The elements of an electrolyte are named ions (ion, going), the anion being the body (in sulphate of copper solution, the acid) which goes up to the positive pole, to the anode of the decomposing body, whilst the cation is that (in sulphate of copper solution, the metal) which goes down to the negative pole, to the cathode of the decomposing body.