The first includes all classes of gun powders used in firearms of all kinds; the second, explosives used in shell, torpedoes, and for demolitions; the third, those explosives used to originate explosive reactions in the two first classes. Corresponding names are given to the phenomena characteristic of each class of explosives, (1) explosions proper, of low order, progressive, or combustions, (2) detonations, of high order, (3) fulminations, this last possessing exceptional brusqueness.
The explosion of low order is marked by more or less progression; the time element is involved as a controlling factor, the time required to complete the explosive reaction being large compared with that of the other forms of explosion.
The second class of explosion is of a different nature. The explosive reaction is not limited or confined to the surfaces exposed but appears to progress in all directions throughout the mass radially from the point of initial explosion. It has been determined experimentally that the velocity of propagation of the explosive wave throughout a mass of guncotton is from 17,000 to 21,000 feet per second.
Fulmination is a class of explosion still more brusque than the last. The abruptness of their explosion and the consequent sharpness of the blow and the concentration of heat on the point of ignition constituting their efficiency as originators of explosions of the first two classes.
Methods of Exploding. Explosives may be exploded by three methods; in reality but two, by heat and by application of energy as by a blow. The heat may be applied directly by friction, by electricity and detonating cap, these two methods of applying the heat giving rise to the three practical methods above mentioned. As it is not practical to apply heat directly to the charge, small charges of special explosives are made up into primers and these are exploded in one of the ways above mentioned and so communicate the explosion to the main charge. Fulminate of mercury is one of the high explosives fulfilling the requirements and it is readily exploded by any one of the methods mentioned. It is used in all detonating caps. Primers for cannon also contain an additional charge of black powder to increase the flame. For this purpose also igniting charges of black powder are attached to the smokeless powder charges for the larger calibers.
Uses. The chief use of low or progressive explosives is as a propelling charge in guns and for blasting where it is desired to exert a pushing effect rather than a blow. High explosives are used when it is desired to exert a high pressure and shatter the container, as in a shell, mine, etc. This class is not satisfactory as a propelling charge for the reason that its rapidity of action is so great that the pressure exerted would burst the gun before the projectile could start. Low explosives are not satisfactory shell fillers for the reason that their action is so low that the shell would break at its weakest point before all the explosives had exploded and what remained would be wasted. With a high explosive, all or most of the charge explodes before the shell can break up. The greater the rapidity of action of an explosive the finer the fragmentation of the projectile. With too rapid action the pieces are too small; with too slow action they are too large. Experience teaches the proper rapidity of action to attain the fragmentation most efficient against animate and material targets.
Propelling Charges. Up to the present time nitrocellulose powder has complied better with the requirements of a suitable, smokeless powder than any other that has been proposed and is used in our service for propelling charges in guns. The danger of manufacture is also less than that of nitroglycerine powders. Moreover the latter, which was formerly used in our service and still is in the British and some others, causes too much erosion of the tubes due to the greater heat of explosion. It has the advantage of requiring a smaller charge for the same muzzle velocity and therefore a smaller powder space and consequent lighter weight of gun.
Shell Fillers. High explosives for shell fillers. Up to the present explosive “D,” trinitrotoluol and picric acid are the principal high explosives which fulfill the requirements as shell fillers. Explosive “D” on account of its great insensitiveness to shock is used in armor piercing projectiles and also in field gun and howitzer shell. It is detonated by a fuze. Trinitrotoluol is used in submarine mines and in general demolition work as it is much easier to explode than explosive “D.”
Table of Explosives. The following table gives a good idea of the principal explosives in use in our service and the characteristics of each:
| Purpose. | High or Low. | Name. |
| Propelling charge in guns. | L | Nitrocellulose, smokeless powder. |
| Bursting charge, projectiles. | H | Picric acid, explosive “D” (powder form) Trinitrotoluol. |
| Blank, saluting charges. | L | Black Powder. |
| Re-inforce charges, primers. | L | Black Powder. |
| Base charge, shrapnel. | L | Black Powder. |
| Time trains, fuzes. | L | Black Powder. |
| Igniting charges, cannon. | L | Black Powder. |
| Charges, submarine mines. | H | Trinitrotoluol wet guncotton. |
| Igniting elements, fuzes and primers. | H | Fulminate of mercury, chlorate of potash (potassium chlorate). |