The copper dross is melted up in a small reverberatory furnace, together with galena from Wisconsin (containing 80 per cent. lead), for work-lead and lead-copper matte, the latter containing about 35 per cent. of copper; this matte is enriched to 55 per cent. copper by the addition of roasted matte, and is finally worked up for crude copper (95 per cent.) in a reverberatory furnace. All the copper so produced is used in the parting process for precipitating the silver. The antimonial skimmings are smelted in a reverberatory furnace, together with coke cinder, for lead and a slag rich in antimony, which is reduced to hard lead (27 per cent. antimony, 0.5 per cent. copper, 0.5 per cent. arsenic) in a small blast furnace, 14 ft. high, which has 8 tuyeres.
The softened lead is tapped off into cast-iron desilverizing pots, which usually outlive 200 charges; in isolated cases as many as 300. For desilverizing, zinc from Pueblo, Colo., is added in two instalments, being mixed in by means of a Howard stirrer. After the first addition there remains in the lead 7 oz. of silver per ton; after the second only 0.2 oz. The first scum is pressed in a Howard press and distilled; the second is ladled off and is added to the next charge. The Howard stirrer is driven by a small steam engine suspended over the kettle; the Howard press by compressed air.
For distilling zinc scum, 12 Faber du Faur tilting retorts, heated with petroleum residue, are used. The argentiferous lead (with 9.6 per cent. silver) is transferred from the retort to a pan lined with refractory brick, which is wheeled to the cupelling hearth and raised by means of compressed-air cylinders, so as to empty its molten contents through a short gutter upon the cupelling hearth. The cupelling hearths are of the water-cooled English type, and are heated by coal with under-grate blast. The cast-iron test rings, with reinforcing ribs, are made in two pieces, slightly arched and water-cooled; they are rectangular, with rounded corners, and are mounted on wheels. The material of the hearth is marl.
Argentiferous lead is added as the operation proceeds, and finally the doré bullion is poured from the tilted test into thick bars (1100 oz.) for parting.
The desilverized lead is refined in charges of 28 tons (4 to 5 hours) and 80 to 90 tons (8 to 10 hours), introducing steam through four to eight half-inch iron pipes. The first skimmings contain a considerable proportion of antimony and are therefore added to the charge when reducing the antimonial slags in the blast furnace. The litharge is worked up in a reverberatory furnace for lead of second quality. The refined lead is tapped off into a kettle, from which it is cast into bars through a siphon.
The parting of the doré bullion is carried out in tanks of gray cast iron, in which the solution is effected with sulphuric acid of 60 deg. B. The acid of 40 deg. B. condensed from the vapors is brought up to strength in leaden pans. In a second larger tank, which is slightly warmed, a little gold deposits from the acid solution of sulphates. The solution is then transferred (by the aid of compressed air) to the large precipitating tank, and diluted with water. It is here heated with steam, and the silver is rapidly precipitated by copper plates (125 plates 18 × 8 × 1 in.) suspended in the solution from iron hooks covered with hard lead. After the precipitation, the vitriol lye is siphoned off, the silver is washed in a vat provided with a false bottom, is removed with a wooden shovel, and is pressed into cakes 10 × 10 × 6 in.
The refining is finished on a cupelling hearth fired with petroleum residue, adding saltpeter, and removing the slag by means of powdered brick. After drawing the last portion of slag the silver (0.999 fine) is kept fused under a layer of wood-charcoal for 20 minutes, and is then cast into iron molds, previously blackened with a petroleum flame. The bars weigh about 1100 oz.
The gold is boiled with several fresh portions of acid, is washed and dried, and finally melted up with a little soda in a graphite crucible. It is 0.995 fine.
The lye from the silver precipitation, after clearing, is evaporated down to 40 deg. B. in leaden pans by means of steam coils, and is transferred to crystallizing vats. The first product is dissolved in water, the solution is brought up to 40 deg. B. strength, and is allowed to crystallize. The purer crystals so obtained are crushed, and are washed and dried in centrifugal apparatus; they are then sifted and packed in wooden casks in two grades according to the size of grain. The very fine material goes back into the vats. From the first strongly acid mother liquor, acid of 60 deg. B. is prepared by concentrating in leaden pans, and this is used for the parting operation.