Air enters at a pressure of about 24 oz. and the time taken for conversion is about four hours. The sulphur contents are reduced to about three per cent. It is found that the top of the charge is not so well converted as the interior. There is practically no loss of lead or silver due to volatilization and very little due to escape of zinc. It has also been found that practically all the limestone fed into the Ropp is converted into calcium sulphate; also that a considerable portion of lead becomes sulphate, and it is considered that lead sulphate is as necessary for the process as galena.
The value of the process may be judged from the fact that better work is now done with 8 blast furnaces than was done with 13 before the process was adopted. In addition to the sintered product from the Huntington-Heberlein pots, sintered slime, obtained by heap roasting, and flux consisting of limestone and ironstone, are fed into the furnaces, which take 2000 long tons per day of ore, fluxes and fuel. The slags now being produced average: SiO2, 25 to 26 per cent.; FeO, 1 to 3 per cent.; MnO, 5 to 5.5; CaO, 15.5 to 17; ZnO, 13; Al2O3, 6.5; S, 3 to 4; Pb, by wet assay, 1.2 to 1.5 per cent.; and Ag, 0.7 oz. per ton. Although this comparatively large quantity of sulphur remains, yet no matte is formed.
THE HUNTINGTON-HEBERLEIN PROCESS AT FRIEDRICHSHÜTTE[29]
By A. Biernbaum
(September 2, 1905)
Nothing, for some time past, has caused such a stir in the metallurgical treatment of lead ores, and produced such radical changes at many lead smelting works, as the introduction of the Huntington-Heberlein process. This process (which it may be remarked, incidentally, has given rise to the invention of several similar processes) represents an important advance in lead smelting, and, now that it has been in use for some time at the Friedrichshütte, near Tarnowitz, in Upper Silesia, and has there undergone further improvement in several respects, a comparison of this process with the earlier roasting process is of interest.
At the above-mentioned works, up to 1900 the lead ore was treated exclusively (1) by smelting in reverberatory furnaces (Tarnowitzeröfen), and (2) by roasting in reverberatory-sintering furnaces roasted material in the shaft furnace. The factor which determined whether the treatment was to be effected in the reverberatory-smelting or in the roasting-sintering furnace was the percentage of lead and zinc in the ores; those comparatively rich in lead and poor in zinc being worked up in the former, with partial production of pig-lead; while those poorer in lead and richer in zinc were treated in the latter. About two-fifths of the lead ores annually worked up were charged into the reverberatory-smelting furnaces, and three-fifths into the sintering furnaces.
In 1900 there were available 10 reverberatory-smelting and nine sintering furnaces. These were worked exclusively by hand.
The sintered product of the roasting furnaces, and the gray slag from the reverberatory-smelting furnaces, were transferred to the shaft furnaces for further treatment, and were therein smelted together with the requisite fluxes. Eight such furnaces (8 m. high, and 1.4 m., 1.6 m., and 1.8 m. respectively in diameter at the tuyeres), partly with three and partly with five or eight tuyeres, were at that time in use.