The nitrogen from these organic sources does not appear on the market as such. Instead, the products enter in bulk into the make-up of fertilizer. They are of miscellaneous character, and only part of what is contributed collects to pass through industrial channels where its flow may be measured. The industrial flow goes on record and the records are available, but even here the nitrogen content has never been systematically computed, so the record is inadequate. For the rest, the portion that does not reach the channels of industry, there is nothing whatever in the way of data to go by. Taken all in all, then, the significance of the organic nitrogen resources is largely conjectural. This is unfortunate. Approximate figures covering the use of organic nitrogen would be of value in various connections, as in the interests of intelligent allocation in times of nitrogen shortage, as helping to determine the extent to which the growing demands of agriculture incident to the growth of population may be discounted from the consequent expansion of scavenging opportunity, or as affording a basis for estimating the very considerable influence of motorization toward increasing the demand for chemically prepared fertilizers.
As things stand, all such questions of relationship lead only to profitless speculation. Even the relative importance of the organic sources as a whole in the economics of nitrogen supply is uncertain. What they have to offer of undeveloped reserves, now taking the form of wasteful sanitation procedure, will be taken up later. Under existing conditions, it is probably fair to assume that 40 to 50 per cent. of the nitrogen normally put to use in the United States is organically associated.
Carboniferous Deposits.
—Nitrogen in its organic relationships is bound up with carbon, of which organic matter is largely composed, and the bond between the two is entirely disestablished only as the carbon itself loses its substantial form through oxidation. In consequence of this enduring alliance, nitrogen is characteristically present in carboniferous deposits, a form of occurrence giving rise to still another, a fourth type of nitrogen resource. Coal and oil-shale loom up as the outstanding representatives of this class. In each, the nitrogen content is variable, but amounts to 1 per cent. or over. With so low a percentage of nitrogen, it goes without saying that neither of these is to be regarded as a possible source of direct supply. The cost would be prohibitive, even under the stress of the most extreme emergency. The nitrogen in a coal bed or an oil-shale formation is as worthless as the iron in any ordinary rock. But coal has other uses, and so has oil shale, or at least will shortly. The nitrogen does not have to be extracted; it gets released incidentally, and when its release is effected under conditions that prevent its escape, the result is a productive nitrogen resource. The nitrogen from this type of resource is in the form of ammonia, the relative importance of which is shown in [Figures 16] to [18] and [Table 66].
GENERAL ASPECTS OF CONTROL
Such is the nature of the nitrogen resources. The resource situation as a whole is represented graphically in [Figure 15]. None other can compare with it for inclusiveness. Its sources are animal, vegetable, mineral, and atmospheric, which is to say, universal; and out of this unparalleled diversity has grown an industrial development as complex as it is diversified, and, incidentally, in view of its bearing on food and munitions supply, as important as it is complex. The situation at best can be but imperfectly grasped, for it has been but inadequately studied. In transgressing all set rules of resource occurrence, it transgresses the limits set for organized investigation. Geologists have studied one phase of the situation, electrochemists another, sanitation experts another, and so on; and the various commercial interests involved have seen to the giving of publicity where publicity would do the most good.
Table 66.—Statistics of Nitrogen Production
| Year | Organic nitrogen | Chemical nitrogen | ||||||||||
|---|---|---|---|---|---|---|---|---|---|---|---|---|
| Dried blood; tankage; guano; fish scrap; cotton seed cake and meal; etc. | Sodium nitrate | Fixation compounds | By-product ammonium sulphate | |||||||||
| World’s production, tons | Domestic production, tons | Imports, tons | World’s production | Domestic production, tons | Imports, tons | World’s production, tons | Domestic production, tons | Imports, tons | ||||
| Ammon. sulph. (Haber), tons | Calcium nitrate (Arc), tons | Cyanamid, tons | ||||||||||
| 1900 | Data for organic nitrogen indefinite,but probably about equal to the total for chemical nitrogen. | ... | ... | ... | ... | ... | ... | ... | ... | 540,000 | 27,600 | 8,411 |
| 1901 | 1,328,664 | ... | 203,960 | ... | ... | ... | ... | ... | 580,000 | 29,279 | 14,486 | |
| 1902 | 1,349,300 | ... | 205,245 | ... | ... | ... | ... | ... | 600,000 | 36,124 | 18,146 | |
| 1903 | 1,485,279 | ... | 272,947 | ... | ... | ... | ... | ... | 640,000 | 41,873 | 16,777 | |
| 1904 | 1,559,091 | ... | 228,012 | ... | ... | ... | ... | ... | 650,000 | 54,664 | 16,667 | |
| 1905 | 1,754,605 | ... | 321,231 | ... | ... | ... | ... | ... | 694,575 | 65,296 | 15,288 | |
| 1906 | 1,800,500 | ... | 372,222 | ... | ... | 386 | ... | ... | 778,365 | 75,000 | 9,182 | |
| 1907 | 1,846,036 | ... | 364,610 | ... | ... | 1,874 | ... | ... | 906,255 | 99,300 | 30,114 | |
| 1908 | 1,970,974 | ... | 310,713 | ... | ... | 2,767 | ... | ... | 970,200 | 83,400 | 38,238 | |
| 1909 | 2,110,961 | ... | 428,429 | ... | 45,450 | 12,734 | ... | ... | 987,840 | 106,500 | 42,914 | |
| 1910 | 2,465,415 | ... | 529,172 | ... | ... | 22,596 | ... | 764 | 1,104,705 | 116,000 | 92,342 | |
| 1911 | 2,521,023 | ... | 544,878 | ... | ... | 59,479 | ... | 5,617 | 1,206,135 | 127,000 | 94,633 | |
| 1912 | 2,585,850 | ... | 486,352 | ... | ... | 115,688 | ... | 7,134 | 1,356,075 | 165,000 | 59,542 | |
| 1913 | 2,772,254 | ... | 625,862 | 20,000 | 181,800 | 173,026 | ... | 14,656 | 1,532,475 | 195,000 | 65,775 | |
| 1914 | 2,463,356 | ... | 541,715 | 60,000 | ... | 208,070 | ... | 29,536 | 1,320,000 | 183,000 | 75,010 | |
| 1915 | 1,755,291 | ... | 772,190 | 150,000 | ... | 845,388 | ... | 20,564 | 1,690,000 | 249,000 | 36,370 | |
| 1916 | 2,912,893 | ... | 1,218,423 | 300,000 | ... | 1,053,439 | ... | 38,023 | 2,000,000 | 285,000 | 12,962 | |
| 1917 | 2,950,000 | ... | 1,555,839 | 500,000 | 300,000 | 954,765 | ... | 44,146 | ... | 325,000 | ||
| 1918 | 2,900,000 | ... | 1,845,192 | ... | ... | ... | ... | 43,070 | ||||
Fig. 15.—Nitrogen sources and their cycles of utilization.