During the long period occupied by his repeated trials of invention he passed through almost every calamity to which human flesh is heir. Again and again he was thrown into prison. Repeatedly he saw starvation staring him and his gentle wife and his poor little children in the face. He was reduced many times to the very last extreme of penury. His friends sneered at him, deserted him, called him mad. He was forced many times to beg the loan of a few dollars, with no prospect of repayment. One of his children died in the dead of winter, when there was no fuel in the cheerless house. A gentleman was once asked what sort of a looking man Goodyear was. "If you meet a man," was the reply, "who wears an India-rubber coat, cap, stock, vest, and shoes, with an India-rubber money purse without a cent in it, that is Charles Goodyear."

Once, while in the extremity of want, when he was living at Greenwich, near New York, he met his brother-in-law, and said, "Give me ten dollars, brother; I have pawned my last silver spoon to pay my fare to the city."

"You must not go on so; you cannot live in this way," said the other.

"I am going to do better," replied Goodyear cheerily.

It was by accident at last that he hit upon the secret of how to make India-rubber durable. He was talking one day to several visitors, and in his ardor making rapid gestures, when a piece of rubber which he was holding in his hand accidentally hit against a hot stove. To his amazement, instead of melting, the gum remained stiff and charred, like leather. He again applied great heat to a piece of rubber, and then nailed it outside the door, where it was very cold. The next morning he found that it was perfectly flexible; and this was the discovery which led to that successful invention which he had struggled through so many years to perfect. The main value of the discovery lay in this, that while the gum would dissolve in a moderate heat, it both remained hard and continued to be flexible when submitted to an extreme heat. This came to be known as the "vulcanization" of India-rubber.

Two years were still to elapse, however, before Goodyear could make practical use of his great discovery. He had tired everybody out by his previous frequent assertions that his invention had been perfected, when it had until now always proved a failure. Many a time he had gone to his friends, declaring that he had succeeded, so that when he really had made the discovery nobody believed in it.

He was still desperately poor and in wretched health. Yet he moved to Woburn, in Massachusetts, resolutely continuing his experiments there. He had no money, and so baked his India-rubber in his wife's oven and saucepans, or hung it before the nose of her tea-kettle. Sometimes he begged the use of the factory ovens in the neighborhood after the day's work was over, and sold his children's very school-books in order to supply himself with the necessary gum. At this time he lived almost exclusively on money gifts from pitying friends, who shook their heads in their doubts of his sanity. Often his house had neither food nor fuel in it; his family were forced to go out into the woods to get wood to burn. "They dug their potatoes before they were half-grown, for the sake of having something to eat."

Goodyear was terribly afraid that he should die before he could make the world perceive the great uses to which his discovery might be applied. What he was toiling for was neither fame nor fortune, but only to confer a vast benefit on his fellow-men.

At last, after infinite struggles, the absorbing purpose of his life was attained. India-rubber was introduced under his patents, and soon proved to have all the value he had, in his wildest moments, claimed for it. Success thus crowned his noble efforts, which had continued unceasingly through ten years of self-imposed privation. India-rubber was now seen to be capable of being adapted to at least five hundred uses. It could be made "as pliable as kid, tougher than ox-hide, as elastic as whalebone, or as rigid as flint." But, as too often happens, his great discovery enriched neither Goodyear nor his family. It soon gave employment to sixty thousand artisans, and annually produced articles in this country alone worth eight millions of dollars.

Happily the later years of the noble, self-denying inventor were spent at least free from the grinding penury and privations of his years of uncertainty and toil. He died in his sixtieth year (1860), happy in the thought of the magnificent boon he had given to mankind.