H. O. H.; CH3. O. H.; CH3. O. CH3; and NH3; NH2; H3; NH(CH3)2; and N(CH3)3; the first representing compounds following the water type, the latter the ammonia type. This suggestion had been previously made by Laurent, in 1846. But Williamson extended his views to inorganic compounds; thus, sulphuric acid was represented as constructed on the double water type—HO. SO2. OH, being derived from H. O. (H. H) O. H, the two hydrogen atoms enclosed in brackets being replaced by the radical SO2. To these types Gerhardt added the hydrogen and hydrogen chloride types, H.H. and H.Cl; and, later, Kekulé, professor in Bonn (1829), added the marsh gas type C(H)4. The next important step was taken by Frankland, professor in the Royal School of Mines, London; his work, however, had been anticipated by Cunn Brown, professor at Edinburgh University, in a pamphlet even yet little known. It was to attribute to elements one or more powers of combination. To these he gave the name “valency,” and the capacity of possessing valency was called “quantivalence.” Thus hydrogen was taken as a “monad,” or monovalent. Chlorine, because it unites with hydrogen atom to atom, is also a monad. Oxygen, having the power to combine with two atoms of hydrogen, was termed a dyad, or divalent; nitrogen a triad, or trivalent; carbon a tetrad, or tetravalent, and so on. This is evident from inspection of the formulas of their compounds with hydrogen, thus:
H H H
/ \ /
H——Cl; H——O——H; H——N ; C
\ / \
H H H
Instances of penta, hexa, and even hepta-valency are not wanting.
This was the key to unlock the structure of chemical compounds; and Frankland’s views, just stated, are still held by chemists. The determination of the constitution of compounds, chiefly those of carbon, occupied the attention of chemists, almost exclusively, until 1880. The plan of action is much the same as that of a mechanician who wishes to imitate a complicated mechanism. He must first dissect it into groups of mechanical contrivances; these are next constructed; and they are finally built together into the complete machine. In certain cases the atoms of carbon are arranged in “chains,” as, for example, in pentyl alcohol:
H3C——C——C——C——C——O——H
H2 H2 H2 H2
each atom being tetrad, and its “affinities,” or powers of combination, saturated either with hydrogen or with those of neighboring atoms of carbon; in others they are in the form of a “ring,” as in benzene, the formula of which was first suggested by Kekulé, viz.:
H H
C——C
/ \
HC CH;
\ /
C==C
H H
or in both, as in ethyl benzene,
H H
C——C
/ \ H H
HC C——C——CH.
\ / H H
C==C
H H
One or more atoms of nitrogen, or of oxygen, may form part of the circle, as in pyridine: