The Progress of the Century

by Unknown

One of the most skillful and successful experimenters in heat was also a Frenchman, Henri Victor Regnault (1810–78). He greatly improved the construction and use of the thermometer, and was the first to discover that the indications of an air thermometer and one of mercury did not exactly agree, because they did not expand in the same degree for equal increases of temperature. His most important work was on the expansion of gases, vapor pressure, specific heat of water, etc., and for careful, patient measuring he had a positive genius. Until he proved the contrary it had been assumed that all gases had the same coefficient of expansion, and Boyle’s law that the volume of a gas was inversely proportional to its pressure had not been questioned. His tables of the elastic force of steam have been of immense practical value, but his studies of the expansion of gases are of greater interest because they have pointed the way to one of the most important accomplishments of the century, the liquefaction of all known gases.

During the earlier years of this century it was the custom to consider vapors and gases as quite distinct forms of matter. Vapors always came, by evaporation, from liquids, and could always be “condensed” or reduced to the liquid form without difficulty, but it was not thought possible to liquefy the so-called “permanent” gases. The first man to attack the problem systematically was Michael Faraday, who, before the end of the first third of the century, had liquefied several gases, mostly by producing them by chemical reactions under pressure. Several of the more easily reducible gases or vapors, such as ammonia, sulphurous acid, and probably chlorine, had been previously liquefied by cold, but a quarter of a century elapsed after Faraday’s researches before the true relation of the liquid and gaseous states of matter was understood, and it was found that both increase of pressure and lowering of temperature were, in general, essential to the liquefaction of a gas. It was Thomas Andrews, of Belfast, who first showed, in a paper published in 1863, that there was a continuity in the liquid and gaseous states of matter, that for each substance there was a critical temperature at which it became a homogeneous fluid, neither a liquid nor a gas: that above this temperature great pressure would not liquefy, while below it the substance might exist as partly liquid and partly gas. He pointed out the fact that for the so-called permanent gases this critical temperature must be exceedingly low, and if such temperature could be reached liquefaction would follow.

Subsequent progress in the liquefaction of gases came about by following this suggestion. Very low temperatures were produced by subjecting the gas to great reduction in volume by pressure, removing the heat of compression by conduction and radiation, and then by sudden expansion its temperature was greatly lowered. As early as 1877 two Frenchmen, Pictet and Cailletet, had succeeded in liquefying oxygen, hydrogen, nitrogen, and air. During the past twenty years great improvements have been made in the methods of accomplishing these transformations, so that to-day it is easy to produce considerable quantities of all of the principal gases in a liquid form, and by carrying the reduction in temperature still further portions of the liquid may be changed to the solid state. The most important work along this line has been done by Wroblewski and Olszewski, of the University of Cracow, and Professor Dewar, of the Royal Institution in London. Temperatures as low as about two hundred and fifty degrees C. below the freezing-point of water have been produced, the “absolute zero” being only two hundred and seventy-three degrees C. below that point. These experiments promise to throw much light on the nature of matter, and they are especially interesting as revealing its extraordinary properties at extremely low temperatures. Among the most curious and suggestive is the fact that the electrical resistance of pure metals diminishes at a rate which indicates that at the absolute zero it would vanish, and these metals would become perfect conductors of electricity.

The dynamics of heat, or “thermo-dynamics,” was an important field of research in the early part of the century, on account of its practical application to the improvement of the steam-engine. The science was created by Carnot, who, in spite of the fact that his views regarding the nature of heat were erroneous, discovered some of the most interesting relations among the quantities involved, and discussed their applications to the heat engines with great skill. Subsequent contributors to the theory and practice of thermo-dynamics were Clausius, Rankine, Lord Kelvin, and Professor Tait.

The mechanical theory of heat naturally led up to what has already been referred to as the most important generalization in physical science since the time of Newton, the doctrine of

THE CONSERVATION OF ENERGY

This principle puts physics in its relation to energy where chemistry has long been in its relation to matter. If matter were not conservative, if it could be created or destroyed at will, chemistry would be an impossible science. Physics is put upon a solid foundation by the assumption of a like conservatism in energy; it can neither be created nor destroyed, although it may appear in many different forms which are, in general, mutually interconvertible.

Many men have contributed to the establishment of this great principle, but it was actually discovered and proved by the labors of three or four. Although it was practically all done before the middle of the nineteenth century, its general popular recognition did not come until a quarter of a century later. The doctrine was first distinctly formulated by Robert Mayer, a German physician, who published in 1842 a suggestive paper on “The Forces of Inorganic Nature,” which, however, attracted little or no attention. Mayer had not approached the problem from an experimental stand-point, but at about the same time it was attacked most successfully from this side by a young Englishman, James Prescott Joule, son of a wealthy brewer of Manchester, England. Joule made the first really accurate determination of the mechanical equivalent of a given quantity of heat, a physical constant which Rumford had tried to measure, reaching only a rough approximation. Substantially Joule’s result was that the heat energy necessary to raise the temperature of any given mass of water one degree Fahr. is the equivalent of the mechanical energy required to lift that mass through a height of seven hundred and seventy-two feet against the force of the earth’s attraction; and, conversely, if a mass of water be allowed to fall through a distance of seven hundred and seventy-two feet under the action of gravity, and at the end of its motion be instantly arrested, the heat generated will suffice to raise its temperature one degree Fahr. Of such vast importance is this numerical coefficient that it has been called the golden number of the nineteenth century. Since Joule’s time it has been redetermined by several physicists, notably by Professor Rowland, of Baltimore, the general conclusion being that Joule’s number was somewhat, but not greatly, too small.

The first clear and full exposition of the doctrine of the conservation of energy was given by Joule in a popular lecture in Manchester in 1847, but it attracted little attention until a few months later, when the author presented his theory at a meeting of the British Association for the Advancement of Science. Even among scientific men it would have passed without comment or consideration had it not been for the presence of another young Englishman, then as little known as Joule himself, who began a series of remarks, appreciative and critical, which resulted in making Joule’s paper the sensation of the meeting. This was William Thomson, who had been, only a year before, at the age of twenty-two years, appointed professor of natural philosophy at the University of Glasgow, now known as Lord Kelvin, the most versatile, brilliant, and profound student of physical science which the century has produced. From that day to the death of Joule (1889) these two men were closely associated in the demonstration and exploitation of a great principle of which they were at first almost the sole exponents among English-speaking people.

By an interesting coincidence, in the same year in which Joule announced the result of his experiments, the Physical Society of Berlin listened to a paper almost identical with Joule’s in character and conclusions, but prepared quite independently, by a young German physician, Herman von Helmholtz, destined to rank at the time of his death, in 1893, as one of the very first mathematicians of the age, doubtless the first physiologist of his time, and as a physicist with whom not more than one other of the nineteenth century may be compared. Helmholtz’s paper was rejected by the editor of the leading scientific journal of Germany, but his work was so important that he must always share with Joule and Kelvin in the glory of this epoch-making generalization.