Many important contributions to the theory and practice of spectrum analysis have been made since the time of Kirchoff and Bunsen, only two or three of which can be referred to here. Instrumental methods by which spectra are produced and examined have been greatly perfected, and this is especially true of what is known as the “diffraction grating” first used by Fraunhofer. A quarter of a century ago Rutherford, of New York, constructed a ruling engine by means of which gratings on glass and spectrum metal were ruled with a precision greatly exceeding what had before been possible. A few years later Rowland, of Baltimore, made a notable advance in the construction of a screw far more perfect than any before made, producing gratings of a fineness and regularity of spacing far ahead of any others, and especially by the capital discovery of the concave grating, by means of which the most beautiful results have been obtained. Very recently Michelson, of Chicago, has invented the echelon spectroscope, which, although greatly restricted in range, exceeds all others in power of analysis of spectral lines. In his hands this instrument has been most effective in the study of the influence of a strong magnetic field upon the character of the spectrum from light produced therein, a most interesting phenomenon first observed by Zeeman and one which promises to reveal much concerning the relation of molecular activity to light and to magnetic force.
The development of spectrum analysis was necessarily accompanied by a recognition of the identity of radiant heat and light. The study of radiant heat, which was carried on during the earlier years of the century by Leslie, and later by Melloni and Tyndall, by what might be called thermal methods, has been industriously pursued during the last two decades by processes similar to those adopted for visual radiation. The most notable contribution to this work is the invention of the bolometer, by Langley, who, at Allegheny, and later at Washington, has made exhaustive studies of solar radiation in invisible regions of the spectrum, especially among the waves of greater length than those of red light, where he has found absorption lines and bands similar in character to those observed in the visible spectrum. He has also studied the absorption of the earth’s atmosphere, the relation of energy to visual effect, and many other interesting problems, the solution of which was made possible by the use of the bolometer.
Mention must also be made of the invention by Michelson of an interference comparator, by means of which linear measurements by optical methods can be accomplished with a degree of accuracy hitherto unheard of. With this instrument Michelson has determined the length of the international prototype metre in terms of the wave length of the light of a particular spectral line, thus furnishing for the first time a satisfactory natural unit of length.
By far the most important contribution to the theory of light made during the last half of the century is that of Maxwell, who, in 1873, announced the proposition that electro-magnetic phenomena and light phenomena have their origin in the same medium, and that they are identical in nature. This far-reaching conclusion has been generally accepted and formed the basis of much of the most important work in physical research in process of elaboration as the century closed. To some of this reference will presently be made.
ELECTRICITY AND MAGNETISM
In no other department of physical science have such remarkable developments occurred during the past century as in electricity and magnetism, for in no other department have the practical applications of scientific discovery been so numerous and so far reaching in their effect upon social conditions. In a brief review of the contributions of the nineteenth century to the evolution of the telegraph, telephone, trolley-car, electric lighting, and other means of utilizing electricity, it will be possible to consider only a very few of the fundamental discoveries upon which the enormous and rather complex superstructure of to-day rests. Happily these are few in number, and their presentation is all the more important because of the fact that in the popular mind they are not accorded that significance to which they are entitled, if, indeed, they are remembered at all.
The first great step in advance of the electricity of Franklin and his contemporaries (and his predecessors for two thousand years) was taken very near the end of the eighteenth century, but it must be regarded as the beginning of nineteenth-century electricity. Two Italian philosophers, Galvani and Volta, contributed to the invention of what is known as the galvanic or voltaic battery, the output of which was not at first distinctly recognized as the electricity of the older schools. By this beautiful discovery electricity was for the first time enslaved to man, who was now able to generate and control it at times and in such quantities as he desired. Although the voltaic battery is now nearly obsolete as a source of electricity, its invention must always be regarded as one of the three epoch-making events in the history of the science during the past one hundred and twenty years. For three-quarters of a century it was practically the only source of electricity, and during this time and by its use nearly all of the most important discoveries were made. Even in the first decade of the century many brilliant results were reached. Among the most notable were the researches of Sir Humphry Davy, who, by the use of the most powerful battery then constructed, resolved the hitherto unyielding alkalies, discovering sodium and potassium, and at the same time exhibited in his lectures in the Royal Institution in London the first electric arc light, the ancestor of the millions that now turn night into day.
The cost of generating electricity by means of a voltaic battery is relatively very great, and this fact stood in the way of the early development of its applications, although their feasibility was perfectly well understood. Without any other important invention or discovery than that of the voltaic battery much would have been possible, including both electric lighting and the electric telegraph. Indeed, electric telegraphy had long been a possibility, even before the time of Galvani and Volta, but its actual construction and use was almost necessarily postponed until a second capital discovery came to remove most of the difficulties.
This was the discovery of a relation between electricity and magnetism, the existence of which had long been suspected and earnestly sought. A Danish professor, Hans Christian Oersted, was fortunate in hitting upon an experiment which demonstrated this relation and opened up an entirely new field of investigation and invention. What Oersted found was that when a conductor, as a copper wire, carrying an electric current, was brought near a freely suspended magnet, like a compass needle, the latter would take up a definite position with reference to the current. Thus an electric current moved a magnet, acted like a magnet in producing a “magnetic field.” The subject was quickly taken up by almost every physicist in Europe and America. Arago found that iron filings would cling to a wire through which a current was passing, and he was able to magnetize steel needles by means of the current. Ampère, another French physicist, studied Oersted’s wonderful discovery both experimentally and mathematically, and in an incredibly short time so developed it as to deserve the title of creator of the science of electro-dynamics.
The first to make what is known as an electro-magnet was an Englishman named Sturgeon, who used a bar of soft iron bent in a horseshoe form (as had long been common in making permanent steel magnets), and, after varnishing the iron for insulation, a single coil of copper wire was wrapped about it, through which the current from a battery was passed. There were thus two ways of producing visible motion by means of an electric current: that of Oersted’s simple experiment, in which a suspended magnetic needle was deflected by a current, and that made possible by the production, at will, of an electro-magnet. The application of both of these ideas to the construction of an electric telegraph was quickly attempted, and two different systems of telegraphy grew out of them. One, depending on Oersted’s experiment, was developed in England first and afterwards in Europe; the other, that involving the use of signals produced by an electric magnet, was developed in America, and was generally known as the American method. It has long ago superseded the first method in actual practice. Its possibility depended on perfecting the electro-magnet and especially on an understanding of the principles on which that perfecting depended. For the complete and satisfactory solution of this problem we are indebted to the most famous student of electricity America has produced during the century, Joseph Henry. In 1829, while a teacher in the academy at Albany, New York, Henry exhibited an electro-magnet of enormously greater power than any before made, involving all of the essential features of the magnet of to-day. The wire was insulated by silk wrapping, and many coils were placed upon the iron core, the intensity of magnetization being thus multiplied. Henry studied, also, the best form and arrangement of the battery under varying conditions of the conductor. An electro-magnetic telegraph had been declared impossible in 1825, by Barlow, an Englishman, who pointed out the apparently fatal fact that the resistance offered to the current was proportional to the length of the conducting wire and that the strength of the current would be thus so much reduced for even short distances as to become too feeble to be detected. Henry showed that what is known as an “intensity battery” would overcome this difficulty, discovering experimentally and independently the beautifully simple law showing the relation of current to electro-motive force which Ohm had announced in 1827. He also invented the principle of the relay, by which the action of a very feeble current controls the operation of a more powerful local system. It will thus be seen that the essential features of the so-called American system of telegraphy are to be credited to Henry, who had a working line in his laboratory as early as 1832.