II.—Electro-Chemical Action
The theory of definite electrolytical or electro-chemical action appears to me to touch immediately upon the absolute quantity of electricity belonging to different bodies. As soon as we perceive that chemical powers are definite for each body, and that the electricity which we can loosen from each body has definite chemical action which can be measured, we seem to have found the link which connects the proportion of that we have evolved to the proportion belonging to the particles in their natural state.
Now, it is wonderful to observe how small a quantity of a compound body is decomposed by a certain quantity of electricity. One grain of water, for instance, acidulated to facilitate conduction, will require an electric current to be continued for three minutes and three-quarters to effect its decomposition, and the current must be powerful enough to keep a platina wire 1⁄104 inch in thickness red hot in the air during the whole time, and to produce a very brilliant and constant star of light if interrupted anywhere by charcoal points. It will not be too much to say that this necessary quantity of electricity is equal to a very powerful flash of lightning; and yet when it has performed its full work of electrolysis, it has separated the elements of only a single grain of water.
On the other hand, the relation between the conduction of the electricity and the decomposition of the water is so close that one cannot take place without the other. If the water be altered only in that degree which consists in its having the solid instead of the fluid state, the conduction is stopped and the decomposition is stopped with it. Whether the conduction be considered as depending upon the decomposition or not, still the relation of the two functions is equally intimate.
Considering this close and twofold relation—namely, that without decomposition transmission of electricity does not occur, and that for a given definite quantity of electricity passed an equally definite and constant quantity of water or other matter is decomposed; considering also that the agent, which is electricity, is simply employed in overcoming electrical powers in the body subjected to its action, it seems a probable and almost a natural consequence that the quantity which passes is the equivalent of that of the particles separated; i.e., that if the electrical power which holds the elements of a grain of water in combination, or which makes a grain of oxygen and hydrogen in the right proportions unite into water when they are made to combine, could be thrown into a current, it would exactly equal the current required for the separation of that grain of water into its elements again; in other words, that the electricity which decomposes and that which is evolved by the decomposition of a certain quantity of matter are alike.
This view of the subject gives an almost overwhelming idea of the extraordinary quantity or degree of electric power which naturally belongs to the particles of matter, and the idea may be illustrated by reference to the voltaic pile.
The source of the electricity in the voltaic instrument is due almost entirely to chemical action. Substances interposed between its metals are all electrolytes, and the current cannot be transmitted without their decomposition. If, now, a voltaic trough have its extremities connected by a body capable of being decomposed, such as water, we shall have a continuous current through the apparatus, and we may regard the part where the acid is acting on the plates and the part where the current is acting upon the water as the reciprocals of each other. In both parts we have the two conditions, inseparable in such bodies as these: the passing of a current, and decomposition. In the one case we have decomposition associated with a current; in the other, a current followed by decomposition.
Let us apply this in support of my surmise respecting the enormous electric power of each particle or atom of matter.
Two wires, one of platina, and one of zinc, each one-eighteenth of an inch in diameter, placed five-sixteenths of an inch apart, and immersed to the depth of five-eighths of an inch in acid, consisting of one drop of oil of vitriol and four ounces of distilled water at a temperature of about 60° Fahrenheit, and connected at the other ends by a copper wire eighteen feet long, and one-eighteenth of an inch in thickness, yielded as much electricity in little more than three seconds of time as a Leyden battery charged by thirty turns of a very large and powerful plate electric machine in full action. This quantity, although sufficient if passed at once through the head of a rat or cat to have killed it, as by a flash of lightning, was evolved by the mutual action of so small a portion of the zinc wire and water in contact with it that the loss of weight by either would be inappreciable; and as to the water which could be decomposed by that current, it must have been insensible in quantity, for no trace of hydrogen appeared upon the surface of the platina during these three seconds. It would appear that 800,000 such charges of the Leyden battery would be necessary to decompose a single grain of water; or, if I am right, to equal the quantity of electricity which is naturally associated with the elements of that grain of water, endowing them with their mutual chemical affinity.
This theory of the definite evolution and the equivalent definite action of electricity beautifully harmonises the associated theories of definite proportions and electro-chemical affinity.