At a later period, however, we have the authority of Raschideddin, (minister of the Tartar Khan of Persia,) and of Marco Polo, that the machines of war employed at the siege of Siang Yang were constructed by Arabian or European workmen, and that the Tartars were not at this period themselves able to manufacture such machines. This would tend to negative the belief which has been entertained by some, that the Chinese then used gunpowder as a means of projection, but does not lessen the possibility that the fuses and compositions projected by these machines were of Chinese origin.

In the history of the dynasty of Sang, A.D. 1259, there is a distinct account of a projectile by means of fire as follows:—"In the first year of the period Khaiking, a kind of arms was manufactured called Tho-ho-tsiary, that is to say, 'impetuous fire-lance.' A nest of grains was introduced into a long tube of bamboo, to which fire was set. A violent flame darted forth, and instantly the nest of grains was projected with a noise similar to that of a peacock, which was heard at a distance of about 150 paces."

Upon the whole, it would appear that the Chinese, although the character of their claims to the knowledge of gunpowder has been exaggerated, were in all probability the people among whom mixtures of combustibles with oxygenated substances originated; and this will form one of the many interesting fields of inquiry to be pursued by those skilled in the literature of the Chinese, now that the field is so largely opened to them.

There are obscure passages in writers of a very early period, which speak of thunderbolts being shot from the walls of besieged towns upon the enemy. Philostratus speaks of such; but the indefinite character of these expressions makes their connexion with either Greek fire or gunpowder extremely doubtful.

In the year 883, Nicetas, admiral of the Eastern empire, was sent by the Saracens of Crete to assault Constantinople, and is stated to have burned twenty of their ships with Greek fire.

One of the earliest accounts of its composition is that given by Anna Comnena, who states it was composed of sulphur, bitumen, and naphtha; but the most distinct early receipt for a composition analogous to gunpowder, is that contained in the celebrated book of Marcus Græcus. In the book called Liber Ignium, we have the following receipts:—

"Note. That the fire capable of flying in the air is of twofold composition, of which the first is: One part of colophon and an equal part of sulphur, two parts of saltpetre, and well pulverized, to be dissolved in linseed or laurel oil. A case, or hollowed wood, is then to be charged with it, and ignited. It will fly suddenly to whatever place you wish, and burn up every thing by its fire."

The second sort of flying fire is prepared in this manner:—

"One pound of sulphur vivum, two pounds of charcoal of linden wood or of willow, six pounds of saltpetre, which three things are minutely pounded in a marble mortar. After that you will charge with it a sheath suitable for flying, or for making thunder.

"Note. The sheath for flying ought to be slender and long, and filled with the aforesaid powder well rammed.